In this study, air pollutants were analyzed at a low-industry city on the Silk Road Economic Belt of Northwestern China from 2015 to 2018. The results show that SO2 and CO had a decreasing trend and NO2, O-3, PM2.5, and PM10 had an increasing trend during the study period. The primary characteristic pollutants were PM2.5 and PM10, which were higher than China's Grade II standard. SO2, NO2, CO, PM2.5, and PM10 concentrations showed similar seasonal variation patterns: the highest pollutant concentration was in winter and the lowest in summer. Those pollutants showed a similar diurnal pattern with two peaks, one at 7:00 to 9:00 and another at 21:00 to 22:00. However, O-3 concentration was highest in summer and lowest in winter, with a unimodal diurnal variation pattern. The annual average pollution concentrations in Tianshui in 2017 were substantially lower than the concentrations reported by most cities in China. By examining the meteorological conditions at a daily scale, we found that Tianshui was highly influenced by local emissions and a southwest wind. Potential source contributions and concentration weighted trajectory analyses indicated that the pollution from Gansu, Sichuan, Qinghai, and Shaanxi Province could affect the pollution concentration in Tianshui. The results provide directions for the government to take in formulating regional air pollution prevention and control measures and to improve air quality.

Air pollution is a global issue that often transcends national borders, leading to disputes over environmental concerns and climate-mitigation responsibilities. Between March and July 2020, we collected aerosol samples in Jimunai, a town in western China neighboring Kazakhstan, to assess transboundary air pollution in the region. Our analysis focused on major water-soluble inorganic ions (WSIs), with Ca2+ and SO42- accounting for almost 60% of the total ion loading. The ratio of cations to anions was greater than one (1.33 & PLUSMN; 0.27), indicating alkaline aerosols during the sampling period. Our results suggest that the pollutants measured were primarily sourced from Kazakhstan, as demonstrated by local meteorological data, air-mass trajectory analysis, and pollutant emission inventories in Kazakhstan. Correlation and primary component analysis indicated that NH4+ played an important role in neutralizing NO3- and SO42-, while Cl- was significantly depleted by the probable reaction HNO3 & UARR; + NaCl = HCl & UARR; + NaNO3. These findings highlight the need for continued monitoring and regulation of air pollution sources in the region to address transboundary air pollution.

With Tibetan Plateau higher than 4 km to the west, the location of Sichuan Basin is unique all around the world and provides a good platform to study air pollution in the urban agglomerations over the complex terrain. To fill in the blanks on vertical distributions of PM1 (the particles smaller than 1 mu m) and carbonaceous aerosols within the basin, by means of high topographic relief, PM1 were off-line sampled during 20 January to 2 February 2018 at eight sites with increasing altitudes from the basin to southeastern margins of the Tibetan Plateau. The regional potential sources for each site were revealed by Hybrid-Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model and concentration-weighted trajectory (CWT) method. The lowest carbonaceous aerosol levels occurred at Lixian, while the highest OC (organic carbon) (EC, elemental carbon) was at Hongyuan (the altitude of 3500 m) (Ande, a rural site) due to more primary emissions. The pollutants inside the basin can be transported the altitudes from 2 km to 3 km by vertical dispersion, but they cannot be dispersed to higher altitudes. The vertical stratification of the pollutants was obvious and easily formed high-low-high pattern from Sichuan Basin to southeastern Tibetan Plateau, especially during highly polluted episodes. The regional potential sources significantly varied as the increased altitudes. Regional pollution was significant inside the basin. The sources at the altitudes from 2 km to 3 km originated from southeastern margins of the Plateau and surrounding cities, while those at higher altitudes were transported from southeastern margins of the Plateau. The impact of basic meteorological variables (temperature, wind speed and vapor pressure) on carbonaceous aerosols was opposite between the basin and Plateau sites. This study was essential to understanding formation mechanisms of severe pollution episodes and thus to making control measures for the urban agglomerations inside the mountainous terrain.

The Tibetan Plateau (TP), as a remote and sparsely populated area, is regularly exposed to polluted air masses sourcing from surrounding regions. Atmospheric circulation, as the major driving force generating long-range transport processes of air pollutants, contributes to high-pollution episodes on the TP. Therefore, using reanalysis data from the European Centre for Medium-Range Weather Forecasts for the 2000-2019 period, this paper first classified atmospheric circulation patterns over the study area into nine types (type 1 - type 9). Among them, circulation types 1, 2, 6, and 8 mainly occurred in spring and winter, while circulation types 3, 4, 5, 7, and 9 primarily occurred in summer and autumn. Second, ground-based and satellite remote sensing data were combined to investigate the impact of atmospheric circulation patterns on the properties of aerosols over Central West Asia and their surrounding areas. We detailed how the atmospheric circulation patterns impacted the aerosol optical depth, angstrom ngstro center dot m exponent, and aerosol types at different Aerosol Robotic Network sites in the study area. The results obtained from ground-based data were further verified by those from satellite remote sensing data. Third, backward trajectories and the corresponding potential source contribution function based on the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model were used to explore the impact of atmospheric circulation patterns on regional transport pathways of aerosols. It was found that under circulation types 1, 2, 6, and 8, few HYSPLIT trajectories were sourced from the south direction, while under circulation types 3, 4, 5, 7, and 9, the trajectories originating from the south increased significantly, which could be attributed to the summer monsoon.

The formation mechanism of air pollution events in the Sichuan Basin (SB), which is the fourth most heavily polluted area in China, has not been fully revealed. This study investigated the formation mechanism of a severe air pollution event over the SB using synoptic approaches and model simulations. The results can be summarized as follows: (1) Heavy air pollution in the SB was characterized by low visibility, low atmospheric boundary layer (ABL) height, high temperature, high relative humidity, strong temperature inversion layer, subsidence in the troposphere, high water vapor content between 500 and 900 hPa, southerly winds in the low troposphere, and surface winds with low speed and irregular direction. (2) Air quality in the SB was closely related to the weather system at 700 hPa over the basin. When the 700 hPa weather system affecting the SB was a high-pressure system, the subsidence and stable atmospheric stratification increased the air pollutant concentrations near the ground. When the 700 hPa weather system affecting the SB was a low-pressure system and the basin was in front of this low-pressure system, southwesterly warm and moist airflow and adiabatic subsidence warming formed the thick temperature inversion layer over the basin. As a result, the temperature inversion layer trapped air pollutants in the basin and induced the heavy air pollution event. When the 700 hPa weather system over the SB was a low-pressure system and the basin was behind the low-pressure system, the dry and cold airflow from the north invaded southward to the basin and broke the temperature inversion layer. Consequently, air pollutants dispersed vertically, resulting in decreased concentrations near the ground. (3) Air pollutants from December 17, 2017 to January 4, 2018 were mainly from local emissions. (4) The WRF-Chem model not only reproduced the variations in PM2.5 concentrations, the ABL height, and the height-time cross-sections of temperature, water vapor content, and wind over Chengdu during the air pollution event, but also revealed the formation mechanism of this heavy air pollution event. The results of this study reveal the formation mechanism of winter heavy air pollution events over the SB and help develop effective regional air quality management strategies to reduce the likelihood of local air pollution events and minimize the adverse impacts of air pollution.

The work is devoted to the study of the climatic effects of black carbon (BC) transferred from forest fires to the Arctic zone. The HYSPLIT (The Hybrid Single-Particle Lagrangian Integrated Trajectory model) trajectory model was used to initially assess the potential for particle transport from fires. The results of the trajectory analysis of the 2019 fires showed that the probability of the transfer of particles to the Arctic ranges from 1% to 10%, and in some cases increases to 20%. Detailed studies of the possible influence of BC ejected as a result of fires became possible by using the climate model of the INMCM5 (Institute of Numerical Mathematics Climate Model). The results of the numerical experiments have shown that the maximum concentration of BC in the Arctic atmosphere is observed in July and August and is associated with emissions from fires. The deposition of BC in the Arctic increases by about 1.5-2 times in the same months, in comparison with simulation without forest fire emissions. This caused an average decrease in solar radiation forcing of 0.3-0.4 Wt/m(2) and an increase in atmospheric radiation heating of up to 5-6 Wt/m(2). To assess the radiation forcing from BC contaminated snow, we used the dependences of the change in the snow albedo on the snow depth, and the albedo of the underlying surface for a given amount of BC fallen on the snow. These dependences were constructed on the basis of the SNICAR (Snow, Ice, and Aerosol Radiative) model. According to our calculations, the direct radiative forcing from BC in the atmosphere with a clear sky is a maximum of 4-5 W/m(2) in July and August.

The dynamic characteristics of biomass burning aerosol originated from South Asia are investigated in this research using nearly 9 years of POLDER/GRASP satellite aerosol dataset. The POLDER/GRASP remote sensing data can provide global, repeatable, various, and sufficient real-world aerosol information even in the remote ocean region, which can't be offered by the ground measurement, laboratory observation or model simulation. The MODIS thermal anomalies/fire dataset and HYSPLIT backward trajectory are applied to search the aerosol originated from South Asia biomass burning. The biomass burning aerosol originated from South Asia could transport to and influence the north part of Indian Ocean (including Bay of Bengal and Arabian Sea), the north part of Indo-China Peninsula, South China, and even far to the Pacific Ocean (including part of East China Sea and South China Sea). The chemical, physical and optical characteristics of biomass burning aerosol over land and over ocean show different features and evolution patterns. Such difference is caused by the different ambient environment and different mixed aerosol during the transport process (urban/industrial aerosol over land and sea salt over ocean). During the 48-hours aging process, the volume fraction of black carbon, AAOD and Angstrom Exponent decrease. Meanwhile, the aerosol sphere fraction and SSA increase. The biomass burning aerosol over land shows a more obvious evolution trend than that over ocean. The biomass burning aerosol over ocean generally have higher SSA and lower volume fraction of black carbon, aerosol sphere fraction, AAOD and Angstrom Exponent. The aerosol radiative forcing efficiency also varies between land and ocean, due to their different features of aerosol and surface properties. In general, a negative clear-sky aerosol radiative forcing efficiency (cooling effect) at the TOA is observed. The aerosol cooling effect at the TOA over ocean (-82 W/m(2) on average) is much stronger than that over land (-36 W/m(2) on average). During the 48-hours aging process, a significant enhancement of the negative radiative forcing efficiency at the TOA is found over land. Over ocean, the enhancement of the negative radiative forcing efficiency at the TOA is weaker.

Absorbing aerosols mainly Black Carbon (BC) have potential effects on the hydrological cycle and climate change over the high-altitude regions particularly in South Asia. The BC measurements are sparse in high altitude locations of the world particularly over the Northern regions of Pakistan. This study investigated the diurnal/monthly variations of BC and its climatic impacts during the period of 2016-2017 over four high altitude locations, i.e., Astore, Gilgit, Sost and Skardu located in the Himalaya-Karakorum-Hindukush (HKH) mountain ranges in Northern Pakistan. The Optical Properties of Aerosols and Clouds (OPAC) model was used for the estimation of aerosol optical properties, e.g., Aerosol Optical Depth (AOD), Asymmetry Parameter (AP) and Single Scattering Albedo (SSA) using the BC number density corresponding to the BC mass concentration. Then the model derived optical properties (AOD, AP and SSA), surface reflectance, ozone and water vapor were used in Santa Barbara DISORT Atmospheric Radiative Transfer (SBDART) model for the calculation of BC aerosol radiative forcing (ARF) at the Top Of Atmosphere (TOA), Surface (SUR) and within the ATMosphere (ATM). The results revealed that the mean monthly BC concentrations were maximum during November (3.05 +/- 0.7 mu g/m(3)) as well as in December (3.05 +/- 0.5 mu g/m(3)) at Gilgit and minimum during August (1.1 +/- 0.3 mu g/m(3)) at Sost. Correspondingly, the diurnal variation of BC concentrations displayed strong fluctuations, with high concentrations in the late night and early morning during November and December for Astore and Gilgit, respectively. Generally, the BC concentrations were maximum/minimum in the morning/evening during May, June, August and September at all locations. The correlation of BC with different meteorological parameters showed that the BC has positive correlation with temperature and wind speed, while negative with relative humidity and rainfall. The HYSPLIT back trajectory analysis revealed that air masses arrived the study locations from both long distance (Turkmenistan, Tajikistan, Uzbekistan, Iran, Afghanistan, India, and China) and local sources. The monthly mean maximum and minimum BC ARF values at SUR (TOA) were found to be 43.7 +/- 3.0 W/m(2) (8.2 +/- 0.2 W/m(2)) and 16.4 +/- 1.0 W/m(2) (1.2 +/- 0.1 W/m(2)), respectively, giving an averaged atmospheric forcing of 35.7 +/- 2.3 W/m(2) and 15.2 +/- 1.9 W/m(2).

Biomass burnings either due to Hazards Reduction Burnings (HRBs) in late autumn and early winter or bushfires during summer periods in various part of the world (e.g., CA, USA or New South Wales, Australia) emit large amount of gaseous pollutants and aerosols. The emissions, under favourable meteorological conditions, can cause elevated atmospheric particulate concentrations in metropolitan areas and beyond. One of the pollutants of concern is black carbon (BC), which is a component of aerosol particles. BC is harmful to health and acts as a radiative forcing agent in increasing the global warming due to its light absorption properties. Remote sensing data from satellites have becoming increasingly available for research, and these provide rich datasets available on global and local scale as well as in situ aethalometer measurements allow researchers to study the emission and dispersion pattern of BC from anthropogenic and natural sources. The Department of Planning, Industry and Environment (DPIE) in New South Wales (NSW) has installed recently from 2014 to 2019 a total of nine aethalometers to measure BC in its state-wide air quality network to determine the source contribution of BC and PM2.5(particulate Matter less than 2.5 mu m in diameter) in ambient air from biomass burning and anthropogenic combustion sources. This study analysed the characteristics of spatial and temporal patterns of black carbon (BC) in New South Wales and in the Greater Metropolitan Region (GMR) of Sydney, Australia, by using these data sources as well as the trajectory HYSPLIT (Hybrid Single Particle Lagrangian Integrated Trajectory) modelling tool to determine the source of high BC concentration detected at these sites. The emission characteristics of BC in relation to PM(2.5)is dependent on the emission source and is analysed using regression analysis of BC with PM(2.5)time series at the receptor site for winter and summer periods. The results show that, during the winter, correlation between BC and PM(2.5)is found at nearly all sites while little or no correlation is detected during the summer period. Traffic vehicle emission is the main BC emission source identified in the urban areas but was less so in the regional sites where biomass burnings/wood heating is the dominant source in winter. The BC diurnal patterns at all sites were strongly influenced by meteorology.

Eighteen years of sun/sky photometer measurements at seven worldwide AErosol RObotic NETwork (AERONET) sites in typical biomass burning regions were used in this research. The AERONET measurements were analyzed with the help of Moderate-resolution Imaging Spectroradiometer (MODIS) fire products and the HYbrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model. The variation in the physicochemical and optical properties of biomass burning aerosols (BBAs), as well as their shortwave radiative forcing, was revealed for different vegetation types in different aging periods. The result indicated that, with aerosol aging, the BBA characteristics have a non-negligible evolution trend with obvious clustering features for different burning vegetation types. During the aging process, the volume fraction of black carbon (BC) declined (with a maximum drop of 38%) accompanied by particle size growth (with a maximum increment of 0.017 mu m). Driven by the change in physicochemical properties, the Single Scattering Albedo (SSA) and the asymmetry factor increased as the aerosol aged (with maximum increments of 0.026 and 0.018 for the SSA and asymmetry factor respectively). The grass and shrub type had a higher volume fraction of BC (2.5 times higher than that in the forest and peat type) and a smaller fine mode volume median radius (with a difference of 0.037 mu m from that of the forest and peat type). Such a phenomenon results in a lower SSA (with a difference of 0.103) and asymmetry factor (with a difference of 0.035) in the grass and shrub type when compared to the forest and peat type. Negative (-74 to -30 W/m(2)) clear-sky top of atmosphere (TOA) shortwave radiative forcing, strengthened during the aging process, was generally found for BBA. The BBA in the forest and peat region usually had stronger negative radiative forcing efficiency.