Compacted clays are extensively used as cover barriers to control rainfall infiltration and upward migration of greenhouse gases at municipal solid waste landfills and volatile organic compounds at industrially contaminated sites. Xanthan gum (XG) amendment offers a green and low-carbon solution to improve gas breakthrough pressure and reduce gas permeability of compacted clays, sustainably improve earthen structures. This study aimed to systematically investigate the effects of XG amendment on gas breakthrough pressure, gas permeability, and hydraulic conductivity of compacted clay liners. The gas breakthrough pressure increased from 0.6 kPa to 2.2 kPa (improve similar to 4 times) and the gas permeability decreased from 2.2 x 10(-14) m(2) to 4.8 x 10(-16) m(2) (reduce similar to 200 times) when the XG dosage increased from 0 % to 2 % and apparent degree of saturation was 100 %. Hydraulic conductivity of XG-amended soil at 1 % XG dosage was 2.6 x 10(-10) m/s, which was 3 % of the value measured in unamended soil. Mechanisms of enhanced gas barrier and hydraulic performance were interpreted by the combined effects of (i) soil pore filling substantiated by the analyses of scanning electron microscopy and pore size distribution; (ii) high viscosity of XG hydrogels, validated by the measurement of rheological properties; and (iii) increased diffuse double layer thickness of the amended soils evidenced by the zeta potential analysis.

Biochar, as an environment-friendly soil amendment, has been extensively proposed in landfill cover, primarily for promoting soil hydraulic properties, such as hydraulic conductivity and soil water retention. However, the impact of biochar derived from various feedstocks on soil-biochar mix properties, particularly gas permeability under unsaturated conditions, remains under-explored. This study evaluates how different types of biochar influence gas permeability and soil water retention. Five biochars pyrolyzed using different biomass waste, such as apple wood, reed straw, walnut, corn cob and corn straw, were each mixed with sandy soil in a 5% mass ratio. Gas permeability and hydrological response (water content, matric suction) were measured during wet-dry cycles. Results indicated that biochar amendments generally enhanced water retention compared to bare soil. Apple wood biochar, in particular, significantly improved both water content (reaching 90% of the control's maximum moisture content) and suction (peaking at 2755 kPa), outperforming reed straw, walnut, corn cob and corn straw biochars. This enhancement stems from apple wood biochar's hydrophilic functional groups (e.g., -OH), which improve soil hydrophilicity and water-biochar interactions. Its large specific surface area and tightly arranged micropores further enhance suction. Gas permeability rose with increasing suction, with reed straw and apple wood biochars increasing gas permeability by 196% due to their larger average pore sizes and the formation of more meso-macro pore structures in the sandy soil. Conversely, walnut and corn cob biochars reduced soil permeability, suggesting their suitability for high-pressure applications. These findings guide the use of biochar-amended soil in landfill covers to mitigate gas emissions.