The morphology of sheep wool applied as organic fertilizer biodegraded in the soil was examined. The investigations were conducted in natural conditions for unwashed waste wool, which was rejected during sorting and then chopped into short segments and wool pellets. Different types of wool were mixed with soil and buried in experimental plots. The wool samples were periodically taken and analyzed for one year using Scanning Electron Microscopy (SEM) and Energy-dispersive X-ray Spectroscopy (EDS). During examinations, the changes in the fibers' morphology were observed. It was stated that cut wool and pellet are mechanically damaged, which significantly accelerates wool biodegradation and quickly destroys the whole fiber structure. On the contrary, for undamaged fibers biodegradation occurs slowly, layer by layer, in a predictable sequence. This finding has practical implications for the use of wool as an organic fertilizer, suggesting that the method of preparation can influence its biodegradation rate. (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(SEM)(sic)(sic)(sic)(sic)(sic)X(sic)(sic)(sic)(sic)(EDS)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic).

Most gravel roads leading to rural areas in Ghana have soft spot sections as a result of weak lateritic subgrade layers. This study presents a laboratory investigation on a typical weak lateritic subgrade soil reinforced with non-woven fibers. The objective was to investigate the strength characteristic of the soil reinforced with non-woven fibers. The California Bearing Ratio and Unconfined Compressive Strength tests were conducted by placing the fibers in single layer and also in multiple layers. The results showed an improved strength of the soil from a CBR value of 7%. The CBR recorded maximum values of 30% and 21% for coconut and palm fibers inclusion at a placement depth of H/5 from the compacted surface. Multiple fiber layer application at depths of H/5 & 2 h/5 yielded CBR values of 38% and 31% for coconut and palm fibers respectively. The Giroud and Noiray design method and the Indian Road Congress design method recorded reduction in the thickness of pavement of 56% to 63% for coconut fiber inclusion and 45% to 55% for palm fiber inclusion. Two-way statistical analysis of variance (ANOVA) showed significant effect of depth of fiber placement and fiber type on the geotechnical characteristics considered. (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic),(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic),CBR(sic)(sic)7%(sic),(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic)(sic)H/5(sic)(sic)(sic)(sic)(sic)(sic),CBR(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)30%(sic)21%. (sic)H/5(sic)2H/5(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic),(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)CBR(sic)(sic)(sic)(sic)38%(sic)31%. Giroud&Noiray(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)56%(sic)63%,(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)45%(sic)55%. (sic)(sic)(sic)(sic)(sic)(sic)(ANOVA)(sic)(sic),(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic).

The reasonable value of good gradation characteristic parameters is key in designing and optimising soil-rock mixed high fill embankment materials. Firstly, the DJSZ-150 dynamic-static large-scale triaxial testing instrument was used for triaxial compression shear tests on compacted skeleton structure soil-rock mixture standard specimens. The changes in strength and deformation indicators under different gradation parameters and confining pressure were analysed. Then, based on the Janbu empirical formula, relationships between parameters K, n, and (sigma 1-sigma 3)ult and the coefficient of uniformity Cu and coefficient of curvature Cc were explored. Empirical fitting formulas for Duncan-Chang model constants a and b were proposed, establishing an improved Duncan-Chang model for soil-rock mixtures considering gradation characteristics and stress states. Finally, based on significant differences in particle spatial distribution caused by gradation changes, three generalised models of matrix-block stone motion from different particle aggregation forms were proposed. Results indicate the standard specimen's strength and deformation indicators exhibit significant gradation effects and stress-state correlations. The improved Duncan-Chang model effectively simulates the stress-strain relationship curve under different gradations and confining pressure, with its characteristics explainable based on the matrix block stone motion generalised model.

In highway construction across the southeastern coastal regions of China, granite residual soil is widely used as subgrade fill material in pavement engineering. Its mechanical behaviour under dynamic loads warrants in-depth investigation. Dynamic events such as vehicular traffic and earthquakes are complex, involving multidirectional loads. The dynamic behaviour of soil under bidirectional cyclic loading differs significantly from that under cyclic loading in one direction. A large-scale bidirectional cyclic direct shear apparatus was utilised to carry on a series of horizontal cyclic direct shear tests on granite residual soil with water contents of 14% and 24% at different normal stress amplitudes (sigma a) (0, 100, 200 kPa). Based on these tests, discrete element method (DEM) models were developed to simulate the laboratory tests. The test results revealed that cyclic normal stress increases dynamic shear strength during forward shear but reduces it during reverse shear. The energy dissipation capacity increases with rising sigma a. The dynamic behaviour of granite residual soil is more significantly affected by cyclic normal stress when the water content is higher. The DEM simulation results indicated that as cyclic shearing progresses, the location of the maximum principal stress (sigma 1) shifts from the top of the specimen toward the shear interface. The distribution of the angle between sigma 1 and the x-axis, as well as sigma 1 and the z-axis, transitions from 'M' distribution to 'Arch' distribution. With increasing sigma a, during forward shear, the magnitude of the maximum principal stress increases, and the orientation of sigma 1 rotates toward the normal direction. Conversely, during reverse shear, the magnitude of the maximum principal stress decreases, and its orientation shifts toward the horizontal shear direction. The material fabric anisotropy coefficient decreases with increasing sigma a, while the anisotropy orientation increases with increasing normal stress.

Understanding soil organic carbon (SOC) distribution and its environmental controls in permafrost regions is essential for achieving carbon neutrality and mitigating climate change. This study examines the spatial pattern of SOC and its drivers in the Headwater Area of the Yellow River (HAYR), northeastern Qinghai-Xizang Plateau (QXP), a region highly susceptible to permafrost degradation. Field investigations at topsoils of 86 sites over three summers (2021-2023) provided data on SOC, vegetation structure, and soil properties. Moreover, the spatial distribution of key permafrost parameters was simulated: temperature at the top of permafrost (TTOP), active layer thickness (ALT), and maximum seasonal freezing depth (MSFD) using the TTOP model and Stefan Equation. Results reveal a distinct latitudinal SOC gradient (high south, low north), primarily mediated by vegetation structure, soil properties, and permafrost parameters. Vegetation coverage and above-ground biomass showed positive correlation with SOC, while soil bulk density (SBD) exhibited a negative correlation. Climate warming trends resulted in increased ALT and TTOP. Random Forest analysis identified SBD as the most important predictor of SOC variability, which explains 38.20% of the variance, followed by ALT and vegetation coverage. These findings likely enhance the understanding of carbon storage controls in vulnerable alpine permafrost ecosystems and provide insights to mitigate carbon release under climate change.

An analytical methodology was developed for the first time in this work enabling the simultaneous enantiomeric separation of the fungicide fenpropidin and its acid metabolite by Capillary Electrophoresis. A dual cyclodextrin system consisting of 4 % (w/v) captisol with 10 mM methyl-beta-cyclodextrin was employed in a 100 mM sodium acetate buffer at pH 4.0. Optimal experimental conditions (temperature 25 degrees C, separation voltage -25 kV, and hydrodynamic injection of 50 mbar x 10 s) allowed the simultaneous separation of the four enantiomers in <10.7 min with resolutions of 3.1 (fenpropidin) and 3.2 (its acid metabolite). Analytical characteristics of the method were evaluated and found adequate for the quantification of both chiral compounds with a linearity range from 0.75 to 70 mg L-1, good accuracy (trueness included 100 % recovery, precision with RSD<6 %), and limits of detection and quantification of 0.25 and 0.75 mg L-1, respectively, for the four enantiomers. No significant differences were found between the concentrations determined and labelled of fenpropidin in a commercial agrochemical formulation. The stability over time (0-42 days) of fenpropidin enantiomers using the commercial agrochemical formulation was evaluated in two sugar beet soils, revealing to be stable at any time in one sample, while in the other a decrease of 45 % was observed after 42 days. Individual and combined toxicity of fenpropidin and its metabolite was determined for the first time for marine organism Vibrio fischeri, demonstrating higher damage caused by parent compound. Synergistics and antagonists' interactions were observed at low and high effects levels of contaminants.

Correlations between the mechanical properties and surface scratch resistance of polylactic acid (PLA) are investigated via tensile and scratch tests on samples after degradation in soil for various times. The results show that the tensile yield strength of PLA is inversely proportional to the natural logarithm of the degradation time, and the scratch resistance and fracture toughness of PLA and the temperature rise near the indenter all increase and then decrease. The surface crystallinity of PLA also increases and then decreases, indicating that it and the scratch resistance are closely related. These findings provide useful information about how PLA behaves under degradation conditions. (c) 2025 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution-NonCommercial 4.0 International (CC BY-NC) license (https://creativecommons.org/licenses/by-nc/4.0/).

Root-knot nematodes (RKN) severely reduce watermelon yields worldwide, despite its nutraceutical value. This study investigated the effects of rock dust (RD) and poultry manure (PM) amendments, applied singly or in combination, on RKN suppression and watermelon fruit yield enhancement. A two-trial field experiment was conducted utilizing a randomized complete block design with three replicates. The treatments included RD and PM each applied at 0, 2.5, or 5 t/ha and combined applications of RD and PM at 2.5 or 5 t/ha each. At 60-66 days post-inoculation, root galling and RKN population density were assessed alongside root-shoot weight. The results indicated that root galling in watermelons was reduced by 60-85 % and 67-89 % in the combined RD- and PMtreated plots across the 1st and 2nd trials, respectively, in contrast to the control plots. Likewise, the RKN population was suppressed by 94-99 % in treated plots in both trials, differing from the control plots. Notably, watermelon fruit yield was significantly higher (p < 0.05) in combined RD and PM treated plots, ranging from 24.7 to 33.7 t/ha and 34.6-46.5 t/ha in the 1st and 2nd trials, respectively, compared to control plots with 13.5 t/ha in the 1st trial compared to and 20.9 t/ha yield in the 2nd trial. In conclusion, our study indicates that coapplication of RD and PM effectively reduced RKN damage and enhanced watermelon fruit yield, providing a sustainable strategy for watermelon production.

Soft soil subgrades often present significant geotechnical challenges under cyclic loading conditions associated with major infrastructure developments. Moreover, there has been a growing interest in employing various recycled tire derivatives in civil engineering projects in recent years. To address these challenges sustainably, this study investigates the performance of granular piles incorporating recycled tire chips as a partial replacement for conventional aggregates. The objective is to evaluate the cyclic behavior of these tire chip-aggregate mixtures and determining the optimum mix for enhancing soft soil performance. A series of laboratory-scale, stress-controlled cyclic loading tests were conducted on granular piles encased with combi-grid under end-bearing conditions. The granular piles were constructed using five volumetric proportions of (tire chips: aggregates) (%) of 0:100, 25:75, 50:50, 75:25, and 100:0. The tests were performed with a cyclic loading amplitude (qcy) of 85 kPa and a frequency (fcy) of 1 Hz. Key performance indicators such as normalized cyclic induced settlement (Sc/Dp), normalized excess pore water pressure in soil bed (Pexc/Su), and pile-soil stress distribution in terms of stress concentration ratio (n) were analyzed to assess the effectiveness of the different mixtures. Results indicate that the ordinary granular pile (OGP) with (25 % tire chips + 75 % aggregates) offers an optimal balance between performance and sustainability. This mixture reduced cyclic-induced settlement by 86.7 % compared to the OGP with (0 % TC + 100 % AG), with only marginal losses in performance (12.3 % increase in settlement and 2.8 % reduction in stress transfer efficiency). Additionally, the use of combi-grid encasement significantly improved the overall performance of all granular pile configurations, enhancing stress concentration and reducing both settlement and excess pore water pressure. These findings demonstrate the viability of using recycled tire chips as a sustainable alternative in granular piles, offering both environmental and engineering benefits for soft soil improvement under cyclic loading.

The soil strength of soft clay is influenced by strain rate effect. Models considering strain rate effect always ignore the impact of loading rate on pore pressure and have poor applicability to 3D engineering problems. Based on the classic inelastic core boundary surface model, a logarithmic rate function representing the strain rate effect of soft soil was introduced to the hardening law. A new parameter H was added to adjust the plastic modulus while another new parameter mu is introduced to account for the strain rate effect. A rate-effect boundary surface constitutive model suitable for saturated clay was subsequently proposed. Combined with the implicit integral numerical algorithm and stress-permeability coupling analysis, the innovative model was implemented in the finite element software and validated by comparing with the results of triaxial tests. By analysing the rate-effect of 11 types of soft soil, a formula to calculate the rate parameter was derived. The developed model was used to calculate the undrained vertical bearing capacity and sliding resistance of a movable subsea mudmat. The mudmat frictional coefficient from soil undrained to partial drained and finally undrained state was obtained and compared with those from the Modified Cam-Clay model. Identical results were obtained without considering the rate effect. When considering the strain rate effect on the improvement of soil strength, the friction resistance coefficient initially decreases and then increases with the decrease of the sliding speed, eventually stabilising after reaching the limit value. The rate-effect on the friction resistance coefficient is most prominent under undrained conditions with high sliding speeds. The soil strain rate effect is suggested to be considered in the design of the subsea mudmat avoid underestimating the friction resistance.