There has been a growing interest in controlled low strength material CLSM due to its engineering features, such as self-leveling and early strength development, as well as it potential for utilizing industrial waste. Still, the dynamic properties on CLSM are rarely studied. This study evaluates the feasibility of red mud as a partial aggregate replacement in foamed-lightweight CLSM, incorporating high-carbon fly ash and preformed foam. We varied both the red mud contents RMc and foam volume ratio FVR within the mixtures and examined their impact on unconfined compressive strength and dynamic properties including shear modulus G and damping ratio D. The results reveal that the red mud enhances foam stability, leading to more uniform pore structures and increased porosity, which reduces bulk densities. Despite higher porosity, red mud serves as a strong alkaline activator, enhancing geopolymer reactions of high-carbon fly ash and thereby increasing both compressive strength and initial shear modulus G0. Interestingly, increasing FVR had minimal impact on the D, while higher RMcnotably increased D, highlighting its distinct role in energy dissipation. The red mud-incorporated foamed CLSM exhibits strain-dependent normalized shear modulus G/G0 comparable to that of gravel, while its D is 40-100 % higher than gravel or gravelly soil at shear strain of 1.10-5, which corresponds to typical traffic-induced vibration levels. Moreover, theoretical volumetric-gravimetric relationships are introduced to account for the combined effects of FVR and RMcon CLSM behavior. These findings demonstrate that the red mud included foamed CLSM can be utilized as advanced structural backfill material capable of effectively mitigating the vibrations induced by traffic, low-amplitude seismic events, and mechanical sources.
Water-induced disintegration is a critical issue in soil stabilization. In this study, soda residue (SR) and fly ash (FA) were mixed to improve the properties of high liquid limit clay (HLC), forming soda residue-fly ash stabilized clay (SRFSC), with cement and/or lime for further stabilization. The mix proportions of the SRFSC were optimized by the orthogonal method, using the compaction, unconfined compressive strength, shear, and disintegration tests. Meanwhile, microscopic tests were performed to reveal the possible mechanical mechanisms. The results showed that the SR and FA content are the primary determinants influencing the mechanical properties of SRFSC. When the base proportion is 70 % SR + 20 % FA + 10 % HLC, the strength is highest (2.45 MPa). At this proportion, the specimen with no cementitious material exhibits the best water disintegration resistance (WDR), reaching 107 min. Adding cement and lime can significantly enhance the WDR of the SRFSC, from complete disintegration at 0.28 min to remaining intact after soaking for 28 days. During field application, the cementitious materials content can be adjusted according to the actual conditions. The superior mechanical properties and WDR of SRFSC are mainly due to the good gradation and dense microstructure. The soda residue can provide abundant Ca2+ to enhance both the mechanical properties and WDR of SRFSC.
Red mud is a kind of solid waste, which can be used as engineering roadbed filler after proper treatment. Due to the special physical and chemical properties of red mud, such as high liquid limit and high plasticity index, it may affect the stability of soil. Therefore, red mud can be improved by adding traditional inorganic binders such as lime and fly ash to improve its road performance as roadbed filler. Red mud-based modified silty sand subgrade filler will be affected by dry-wet alternation caused by various factors in practical application, thus affecting the durability of the material. In order to study the strength degradation characteristics and microstructure changes of red mud, lime and fly ash modified silty sand subgrade filler after dry-wet cycle, the samples of different curing ages were subjected to 0 similar to 10 dry-wet cycles, and their compressive strength, microstructure and environmental control indexes were tested and analyzed. The results show that the sample cured for 90 days has the strongest toughness and the best ability to resist dry and wet deformation. With the increase of the number of dry-wet cycles, the mass loss rate of the sample is in the range of 6 similar to 7 %, and the unconfined compressive properties and tensile properties decrease first and then increase. There are continuous hydration reactions and pozzolanic reactions in the soil, but the degree of physical damage in the early stage of the dry-wet cycle is large, and the later cementitious products have a certain offsetting effect on the structural damage. The internal cracks of the sample without dry-wet cycle are less and the structure is dense. After the dry-wet cycle, the microstructure of the sample changed greatly, and the cracks increased and showed different forms. Through SEM image analysis, it was found that the pore structure of the sample changed during the dry-wet cycle, which corresponded to the change law of mechanical properties. After wetting-drying cycles, the leaching concentration of heavy metals in the modified soil increased slightly, but the overall concentration value was low, which was not a toxic substance and could be used as a roadbed material. The study reveals the influence of dry-wet cycle on the strength characteristics and microstructure of red mud, lime and fly ash synergistically improved silty sand, which provides a technical reference for the engineering application of red mud-based materials.
This study investigates the influence of wood pellet fly ash blended binder (WABB) on the mechanical properties of typical weathered granite soils (WS) under a field and laboratory tests. WABB, composed of 50 % wood pellet fly ash (WA), 30 % ground granulated blast furnace slag (GGBS), and 20% cement by dry mass, was applied at dosages of 200-400 kg/m3 to four soil columns were constructed at a field site deposited with WS. After 28 days, field tests, including coring, standard penetration tests (SPT), and permeability tests, revealed enhanced soil cementation and reduced permeability, indicating a denser soil matrix. Unconfined compressive tests (UCT) and free-free resonant column (FFRC) tests on field cores at 28 and 56 days, compared with laboratory specimens and previously published data, demonstrated strength gains 1.2-2.1 times higher due to field-induced stress. The presence of clay minerals influenced the WABB's interaction and microstructure development. Correlations between seismic waves, small-strain moduli, and strength were developed to monitor in-situ static and dynamic stiffness gain of WABB-stabilized weathered granite soils.
Geopolymers are recently recognized as superior sustainable alkali-activated materials (AAMs) for soil stabilization because of their strong bonding capabilities. However, the influence of freeze-thaw cycles (FTCs) on the performance of geopolymer-stabilized soils reinforced with fibers remains largely unexplored. In the current study, for the first time, the durability of polypropylene fiber (PPF) reinforced clayey soil stabilized with fly ash (FA) based geopolymer is investigated under FTCs, evaluating its performance during prolonged seasonal freezing. The effects of repeated FTCs (0, 1, 3, 6, and 12 cycles), different contents of alkali-activated FA (5 %, 10 %, and 15 %), varying PPF percentages (0 %, 0.4 %, 0.8 %, and 1.2 % with a length of 6 mm), and curing time (7 and 28 days) on the properties of stabilized samples have been determined through tests including standard Proctor compaction, unconfined compressive strength (UCS), mass loss, scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), and Fourier transform infrared spectroscopy (FTIR). The results revealed that a 0.4 % PPF concentration maximized strength in FA-based geopolymer samples by restricting crack propagation, irrespective of FA content, number of FTCs, or curing time. However, higher PPF contents lowered UCS values and Young's modulus due to fiber clustering and increased failure strain, respectively. Generally, an initial increase in UCS, Young's modulus, and resilience modulus (MR) of stabilized samples occurred with more FTCs because of their dense structure, delayed pore formation, and continued geopolymerization process and followed by a constant or decreasing trend in strength after 6 (or 3 in some cases) FTCs due to ice expansion in created air voids. Longer curing time resulted in denser samples with improved resistance to FTCs, especially under 12 FTCs. Moreover, samples with 10 % alkali-activated FA demonstrated the least susceptibility to FTCs. While initial FTCs caused no mass loss, subsequent cycles led to increased mass loss and remained below 2 % for all samples. Microstructural analysis results corroborated UCS test results. Although the primary chemical composition remained unchanged after 12 FTCs, these cycles induced morphological changes such as critical void formation and cracking within the gel structure. The stabilization approach proposed in this study demonstrated sustained UCS after 12 FTCs, promising reduced maintenance costs and extended service life in regions with prevalent freeze-thaw damage.
This paper aims to enhance the effective utilization of construction solid waste renewable brick powder (RBP) and circulating fluidized bed fly ash (CFBFA), addressing the issues of resource consumption and environmental pollution associated with these two types of solid waste. It employs CFBFA to synergistically activate RBP for the preparation of solid waste-based earthwork subgrade backfill. This research examines the impact of RBP and CFBFA content on the performance of earthwork subgrade backfill (ESB), while the microstructure of the paste test block was investigated using XRD, SEM, FTIR, and TG-dTG techniques. The synergistic mechanism of multisolid waste was examined at the micro level, and the appropriate ratio of solid waste-derived lowcarbon ESB was thoroughly assessed. The findings indicate that an increase in the CFBFA content generally enhances the mechanical strength of the paste. At the experimental ratio of RBP: CFBFA: coarse-grained soil = 8: 32: 60, the 28-day unconfined compressive strength (UCS), California Bearing Ratio (CBR) value, rebound modulus value, shear strength value, and compression modulus value of the sample attain their maximums, measuring 5.3 MPa, 41.9 %, 71.9 MPa, 10.5 KPa, and 15.76 MPa, respectively, all exceeding the standard values. The hydration products of cementitious materials based on RBP and CFBFA mostly consist of C-S-H gel, ettringite (AFt), and calcite. The robust honeycomb gel structure, created by the staggered interconnection of C-S-H gel and ettringite, is the primary contributor to mechanical strength. The modified cementitious material, composed of RBP-CFBFA, exhibits effective cementation and solidification properties for heavy metals, achieving leaching concentrations that comply with Class III water standards as outlined in the Chinese standard GB/T 14848-2017.
The environmental impact of red mud leachate, particularly from tailings ponds, has become a significant concern due to its highly alkaline nature and potential to cause widespread soil and water contamination. Addressing this issue requires effective strategies for mitigating the leakage of contaminants, such as heavy metals and hazardous alkalis, into surrounding ecosystems. This study explores the use of fly ash-modified clay liners as a solution to contain and treat red mud leachate pollutants, including heavy metals and alkalis. Macro-scale tests, such as permeation and unconfined compression tests, combined with micro-scale analyses (XRD, SEM, BET), investigate the influence of varying fly ash content on the hydraulic conductivity, mechanical properties, and microstructure of the clay liners. The findings show that fly ash significantly reduces the hydraulic conductivity of the liners, improving their effectiveness in preventing seepage. It also enhances the liners' ability to adsorb heavy metal ions and increases their mechanical strength, especially cohesion, with optimal performance at a 9 % fly ash content. The study further reveals that pozzolanic reactions in the alkaline environment of red mud lead to the formation of cementitious gel binders (C-S-H, C-A-H), which reduce pore sizes and create a denser, more impermeable structure. These improvements in both physical and chemical stability demonstrate the potential of fly ash-modified clay liners as an effective, sustainable solution for managing red mud tailings ponds. This study provides valuable support for environmental management of red mud tailings ponds and the sequestration of red mud leachate waste.
As an emerging environmentally friendly solid waste-based composite foam lightweight soil, saponified slag fly ash (SS-FA) foam lightweight soil has a wide range of application prospects in road engineering. In this paper, the dynamic characteristics of SS-FA foam light soil material were investigated. Dynamic triaxial tests under different cyclic loading conditions were designed to analyze the variation rules of dynamic elastic modulus and damping ratio. The results showed that the stress-strain curve of SS-FA foam lightweight soil can be divided into three stages: elastic stage, plateau stage, and stress yielding stage. Under cyclic dynamic load, with the increase of dynamic stress amplitude, the dynamic elastic modulus of 400-700 kg/m3 samples gradually increased to the maximum, reaching 235.24 MPa, 324.54 MPa, 356.45 MPa, 379.67 MPa, respectively. The damping ratio, on the other hand, shows a tendency to first decrease and then slowly increase to stabilize. The dynamic elastic modulus is positively correlated with density grade, confining pressure and loading frequency. The damping ratio decreases with the increase of density grade and loading frequency, and increases with the increase of confining pressure. The electron microscope test was designed and image processing and data statistics were carried out. Through the grey correlation analysis, the correlation degree between the microstructure parameters of SS-FA foamed lightweight soil and the macroscopic mechanical properties is basically above 0.6, indicating that the two have a significant correlation. A normalized prediction formula model between the dynamic elastic modulus of materials and the conditional parameters was established. The R2 of the linear fitting of the predicted value is 0.964, indicating that the prediction model has a high degree of fitting and a good prediction effect. The research results revealed the dynamic mechanical properties of foamed lightweight soil, and provided a reference for the application of SS-FA foamed lightweight soil in subgrade engineering.
The study includes the dynamic characterization of clayey soil blended with nano-SiO2 and fly ash under cyclic loading at high strain. The percentages of nano-SiO2 varied between (0.5-7)%, and fly ash varied between (10-30)% by weight of the soil. The optimal dosages of nano-SiO2 and fly ash were established by employing the outcome of the static test results. The cyclic triaxial (CTX) tests and bender element (BE) tests were carried out to determine the G and D of the composite material and to develop normalized modulus reduction (G/G(max)) and damping ratio curves for the same. The strain-controlled cyclic triaxial tests were conducted for a shear strain range of 0.6-3.0% at a loading frequency of 1 Hz and an adequate confining pressure of 100 kPa. The findings indicated that with the rise in cyclic shear strain (gamma), the G decreases while the damping ratio increases. The hyperbolic models were used to build the curve fitting between the G/G(max) and the damping ratio curve with various gamma. As a result, the correlations between the empirical models fit the database well. The established correlations can be suitable for predicting the seismic behavior of the nano-SiO2 and fly-ash-treated clayey soil under various strain conditions. Furthermore, the carbon footprint and cost analysis of nano-SiO2 and fly ash treated clay soil were compared with the traditional stabilizers. The use of nano-SiO2 and fly ash in stabilizing the clayey soils contributes toward sustainable development and a reduced carbon footprint.
Lateritic clay is widely distributed in southern China, and its strength is greatly affected by water content. The elevated moisture content in lateritic clay during monsoon periods frequently results in insufficient shear strength for standard engineering applications. Large quantities of solid waste, including steel slag, fly ash, and granulated blast furnace slag, are produced as industrial by-products. This paper is based on the backfilling resource utilization of steel slag, fly ash, and ground-granulated blast-furnace slag as lateritic clay improvement admixtures, along with the stress-strain behavior, strength characteristics, and microstructure of steel-slag-modified lateritic clay, fly-ash-modified lateritic clay, and ground-granulated blast-furnace slag-modified lateritic clay, by combining uniaxial compression tests, straight shear tests, and scanning electron microscopy observation. The experimental results were analyzed to determine the appropriate dosages of three kinds of solid waste and their mechanisms in lateritic clay modification. The results indicate that the unconfined compressive strength of SS-modified lateritic clay exhibited an increase with an increase in SS dosage in the range of 1-7%, the unconfined compressive strength of FA-modified lateritic clay showed an increase with an increase in FA dosage in the range of 1-5%, and the unconfined compressive strength of GGBFS-modified lateritic clay increased with an increase in the use of GGBFS in the range of 1-5%. Under the condition of a 7-day curing age, the unconfined compressive strength of lateritic clay modified with 7% SS increased by approximately 397%, while that modified with 5% FA and 5% GGBFS exhibited increases of about 187% and 185%, respectively. The stress-strain relationship of fly-ash and blast-furnace slag-modified lateritic clays showed elastic-plastic deformation. But the stress-strain behavior of steel-slag-modified lateritic clay at a steel slag dose greater than 5% and a maintenance age greater than 7 days showed elastic deformation. Analyzing the SEM images shows that the more hydration products are generated, the relatively higher the unconfined compressive strength of modified lateritic clay is, and the form of deformation of modified lateritic clay is closer to elastic deformation. Through comparative analysis of modified lateritic clay samples, this study elucidates the property-altering mechanisms of waste powder additives, guiding their engineering utilization.