This investigation examines the development of titanium slag-flue gas desulfurized gypsum-Portland cement ternary composites (the ternary composites) for the solidification and stabilization of Pb-contaminated soils. The efficacy of the ternary composites is systematically evaluated using a combination of experimental methodologies, including mechanical properties such as unconfined compressive strength, stress-strain behavior and elastic modulus, leaching toxicity, XRD, TG-DTG, FTIR, XPS, and SEM-EDS analyses. The results indicate that the mechanical properties of Portland cement solidified Pb-contaminated soils are inferior to those of Portland cement solidified Pb-free soil, both in the early and later stages. However, the mechanical properties of Pbcontaminated soils solidified by the ternary composites are superior to those of the ternary composites solidified Pb-free soils in the early stage but somewhat inferior in the later stage. The ternary composites significantly decrease the leached Pb concentrations of solidified Pb-contaminated soils, which somewhat increase with the Pb content and with the pH value decrease of the leaching agent. Moreover, with much lower carbon emissions index and strength normalized cost, the ternary composites have comparable stabilization effects on Pbcontaminated soils to Portland cement, suggesting that the ternary composites can serve as a viable alternative for the effective treatment of Pb-contaminated soils. Characterization via TG-DTG and XRD reveals that the primary hydration products of the ternary composite solidified Pb-contaminated soils include gypsum, ettringite, and calcite. Furthermore, FTIR, XPS and SEM-EDS analyses demonstrate that Pb ions are effectively adsorbed onto these hydration products and soil particles.

This study developed a novel geopolymer (RM-SGP) using industrial solid wastes red mud and slag activated by sodium silicate, aiming to remediate composite heavy metal contaminated soil. The effects of aluminosilicate component dosage, alkali equivalent, and heavy metal concentration on the unconfined compressive strength (UCS), toxicity leaching characteristics, resistivity, pH, and electrical conductivity (EC) of RM-SGP solidified composite heavy metal contaminated soil were systematically investigated. Additionally, the chemical composition and microstructural characteristics of solidified soil were analyzed using XRD, FTIR, SEM, and NMR tests to elucidate the solidification mechanisms. The results demonstrated that RM-SGP exhibited excellent solidification efficacy for composite heavy metal contaminated soil. Optimal performance occurred at 15 % aluminosilicate component dosage and 16 % alkali equivalent, achieving UCS >350 kPa and compliant heavy metal leaching (excluding Cd in high-concentration groups). Acid/alkaline leaching tests revealed distinct metal behaviors: Cu/Cd decreased progressively, while Pb initially declined then rebounded. Microstructural analysis indicated that RM-SGP generated abundant hydration products (e.g., C-A-S-H, N-A-S-H gels), which acted as cementitious substances wrapping soil particles and filling and connecting pores, thereby increasing the soil's compactness and improving the solidification effect. Furthermore, heavy metal ions were solidified through adsorption, encapsulation, precipitation, ion exchange, and covalent bond et al., transforming their active states into less bioavailable forms, proving novel insights into the remediation of composite heavy metal contaminated soils and the resource utilization of industrial solid wastes.

The infiltration and degradation of domestic contaminants have a substantial influence on the mechanical properties of soil. Sucrose is one of the oligosaccharide contaminants with high content and is prone to degradation in domestic-source contaminants. In this study, a series of tests were conducted to investigate the changes in the mechanical properties of clayey soil during the sucrose degradation process. First, in different concentrations of sucrose-contaminated soil, the organic matter content during the sucrose degradation process was measured to analyze its degradation characteristics. During the degradation process, the unconfined compressive strength and compression coefficient of the soil were measured to analyze the changes in its mechanical properties. Finally, the changes in the permeability coefficient and microstructure of the soil were analyzed in depth. The findings indicated that the degradation of sucrose and the associated alterations in the mechanical properties of contaminated soil were concentration-dependent. The effect mechanism involved the formation of organic-clay flocs during the early stages of degradation and the alkaline oxides' dissolution in the later stages. These findings contribute to a deeper understanding of the impact of domestic-source pollution on soil and provide references for the reinforcement of contaminated soil.

To reveal the engineering properties of Zn-contaminated soil solidified with a new cementitious material, namely phosphate rock powder-MgO-cement (PMC), several series of solidified soil characterization tests including moisture content, dry density, pH value, unconfined compressive strength, and stress-strain curve were conducted. The traditional Portland cement was selected for a comparison purpose. The effects of curing time and Zn2 + concentration on these property indexes were investigated to explore the inhibition mechanism of heavy metal Zn2+ on the stabilization process. In addition, the correlations of unconfined compressive strength with three physical property indexes were analyzed. The results indicated that the PMC stabilizer was far superior to the cement for stabilizing Zn-contaminated soil in terms of mechanical properties and environmental impacts. The normalized moisture content of PMC stabilized soil was greater than the cement stabilized soil, indicating a more complete hydration reaction. A small amount of Zn2+ can promote the hydration reaction, but when the Zn2+ concentration exceeded 0.5 %, the hydration reaction was significantly hindered. The dry density of PMC stabilized soil was about 6 % more than cement stabilized soil under the same conditions. The pH values of PMC stabilized samples were much lower than the cement stabilized soil samples and distributed in 8.0-9.5. The stress-strain characteristic of PMC stabilized soil was softening type and the heavy metal Zn2+ was solidified by adsorption, which could make the stress-strain curve of cement stabilized sample change from brittle type to ductile type.

Soil polycyclic aromatic hydrocarbons (PAHs) and cadmium (Cd) pollution poses severe threats to environment security. Previous studies have reported that both nanoparticles and humic acid (HA) have ability to phytoremediate of pyrene/Cd in soil. Here, pot experiments were conducted to investigate the effects of TiO2NPs and humic acid addition on the applicability Hylotelephium spectabile of remediation for pyrene-Cd co-contaminated soil and the corresponding plant growth. The results show that TiO2NPs with HA can mitigate the damage to plant physiology. TiO2NPs-HA is more suitable to be applied on composite soil where Cd pollution is dominant and pyrene pollution is light. Furthermore, the coating of TiO2NPs with HA enhances the availability of Cd and expands root xylem, allowing roots to absorb and accumulate Cd in large quantities finally. This study aims to establish a theoretical foundation for the implementation of sedum plant in remediating soil contaminated with multiple pollutants.

We present an initial study on the use of contaminated soils, effectively treated through a solidification and stabilization (S/S) process that renders them inert, as encapsulated aggregates in the creation of novel metaconcretes. Several mix designs of solidified and stabilized soils are carefully examined, and their physical and mechanical properties are characterized experimentally. These properties are crucial for determining how these treated soils can be effectively incorporated into metaconcretes, a class of materials known for their unique ability to attenuate mechanical waves through resonant structures. The frequency bandgap response of metaconcretes incorporating rubber-coated aggregates made from solidified soils is studied using analytical formulations. The results indicate that the proposed reutilization technique for contaminated soils not only ensures their safety but also offers significant potential for applications in the construction of blast-protective structures and seismic-shielding metamaterials.

Microbially Induced Magnesium Carbonate Precipitation (MIMP) technology provides an innovative method for solidifying and stabilizing heavy metal-contaminated soils. However, the mechanical strength and microstructure of the soil following remediation require further investigation. This study evaluates the mechanical properties of zinc-contaminated soil solidified using MIMP technology under varying zinc ion concentrations, cementing solution concentrations, and curing times. Unconfined compressive strength tests, carbonate production tests, and microscopic analyses are employed to assess microstructural changes. The results indicate that MIMP enhances the unconfined compressive strength of red clay, with significantly higher strength observed in samples without zinc contamination than those with zinc contamination. The maximum unconfined compressive strength is achieved at a cementing solution concentration of 1.25 mol/L and a curing time of 15 days, conditions under which the production of magnesium carbonate also peaks. As the zinc ion concentration increases, the unconfined compressive strength of the samples gradually decrease, accompanied by a reduction in magnesium carbonate production. With longer curing times, the unconfined compressive strength increases while the amount of magnesium carbonate rises and stabilizes. Microscopic analysis reveals that MIMP treatment fills internal pores, reducing their number and enhancing the bonding strength between soil particles. The primary mineral composition consists predominantly of hydromagnesite and magnesium carbonate.

In recent decades, heavy industrial discharges have caused severe soil and groundwater pollution. Many areas previously occupied by industries are now represented by lands contaminated by the accumulation of toxic metals, which pose serious risks to human health, plants, animals, and surrounding ecosystems. Among the various potential solutions, the solidification and stabilization (S/S) technique represents one of the most effective technologies for treating and disposing of a wide range of contaminated wastes. This study focuses on the theoretical definition of a green material mix, which will subsequently be used in the solidification process of contaminated industrial soils, optimizing the mix to ensure treatment effectiveness. The mix design was developed through a literature analysis, representing a preliminary theoretical study. This paper explores the application of the S/S process using various additives, including Portland cement, fly ash (FA), ground granulated blast furnace slag (GGBFS), and other industrial waste materials, to create an innovative mix design for the treatment of contaminated soils. The main objective is to reduce the permeability and solubility of contaminants while simultaneously improving the mechanical properties of the treated materials. The properties of the studied soils are described along with those of the green materials used, providing a comprehensive overview of the optimization of the resulting mixtures.

The solidification effect of contaminated soil degrades under wet-dry (W-D) cycles and acid rain. Acidic dry-wet cycle tests for Cr-contaminated soil solidified by alkali-activated granulated blast furnace slag (GGBS) are carried out. Toxic leaching test and accelerated leaching test are performed to study the leaching characteristic and mechanism. Scanning electron microscopy and energy spectrum analysis are used to investigate the microscopic mechanism. The long-term stability is evaluated through the apparent diffusion coefficient. The results show that a few W-D cycles at pH=7 will cause additional hydraulic reaction of GGBS and thus reduce the leaching concentration of total Cr and Cr(VI). Along with W-D cycles more AFt is generated. The expansion of AFt results in micro-fracture and thus more Cr leaching. In acidic W-D cycles, AFt dissolves first, releasing Cr immobilized by ion exchange. With the increasing acidity, C-S-H gels dissolve and more gypsum is generated, resulting in more micro-fractures. Consequently, the encapsulation effect weakens, resulting in more Cr leaching. However, the C-A-S-H gels remain stable. The slopes of the logarithmic curves of cumulative leached fraction versus time range from 0.373 to 0.675. The errors of fitting by a pure-diffusion analytical solution are mainly below 0.5%, indicating that diffusion is the dominant leaching mechanism. However, after 18 W-D cycles at pH=3, the effect of dissolution increases and the diffusion-dominated criteria are not satisfied. The mobility of Cr under neutral, weak acidic, and strong acidic W-D cycles is low, moderate, and high, respectively. It is necessary to take measures to reduce acid rain infiltration and W-D cycles when utilizing solidified soil. This research provides a reference for evaluating the long-term stability of solidified contaminated soil.

The preparation of geopolymer for solidification/stabilization of heavy metal contaminated soils using industrial solid waste was a sustainable method. In this study, a binary geopolymer curing agent was synthesized from red mud and fly ash for the treatment of copper- and cadmium- contaminated soils. The changes in the properties of the cured soil were investigated by analyzing compressive strength, permeability coefficient, pH value, toxicity leaching, and the chemical forms of heavy metals. These parameters were examined under varying amounts of curing agent and curing time. The solidification mechanism of contaminated soil was revealed by microscopic experiments such as X-ray diffraction (XRD), infrared spectroscopy (FTIR), scanning electron microscope with energy dispersive X-ray spectroscopy (SEM-EDS). The results showed that geopolymer could significantly improved the mechanical properties and environmental safety of contaminated soil. Compressive strengths of Cu and Cd contaminated soils after 28d of curing with 30 % geopolymer were 1.27 and 1.44 MPa, the permeability coefficients were 4.2 and 3.8-6cm/s, and toxic leaching amounts of Cu2+ and Cd2+ were 4.8 and 0.21 mg/L, and pH values were 10.9 and 10.6, respectively. Geopolymer gel structures not only filled the voids between soil particles but also physically encapsulated, chemically bonded, precipitated and ion-exchanged to achieve solidification/stabilization of contaminated soils. This research provided a new technology for the management of heavy metal contaminated soil and promoted the sustainable use of industrial solid waste.