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To decrease the environmental impact and increase the high-quality resource utilization of construction spoil (CS), the alkali-activated slag (AAS) was selected to solidify CS and prepare solidified construction spoil (SCS). SCS with certain working and mechanical properties can be used as building materials, such as unsintered bricks. However, the preparation of SCS is inefficient, mainly because the properties of SCS are affected by various factors, and the formula is difficult to determine. This study intensively investigated the effects of the liquid-solid ratio (W/ (B + S)), clay content of CS, and binder-soil ratio (B/S) on the flowability and compressive strength of SCS. It was found that W/(B + S) was the main factor controlling compressive strength, and both W/(B + S) and clay content significantly affected the flowability of SCS. Based on an assumption for the flowability prediction method and the relationship between flowability and liquid-solid ratio of CS, AAS, and SCS, a method to predict the flowability of SCS was proposed and validated. Additionally, the extended Abrams' law was applied to fit the compressive strength variation of SCS. Combining the flowability prediction method and the extended Abrams' law, a novel formula design method for SCS was proposed and proven effective in validation experiments.

期刊论文 2024-11-01 DOI: 10.1016/j.jobe.2024.110517

Civil excavation projects frequently yield substantial excess spoil, posing challenges to sustainable construction. This study explores repurposing such spoil for creating controlled low strength material (CLSM), emphasizing the novel use of polycarboxylate superplasticizer (PCE) to reduce the water requirement. The work also distinctively utilizes water film thickness (WFT) theory to elucidate the effects of PCE dosage and WFT on material properties, thereby advancing CLSM mix design. First, using an experimental approach, a series of fresh CLSM samples are prepared, with varying the water-to-solid ratio (W/S) and PCE dosage, to evaluate their packing density, WFT, flowability, and bleeding rate. It is demonstrated that both packing density and WFT experienced a non-linear increase with rising PCE dosage. Regression analysis of the experimental data reveals that the flowability and bleeding rate linearly increase with the rising WFT, and the enhancements are more pronounced at higher PCE dosage. Notably, at a given WFT, the impact of PCE dosage on flowability and bleeding rate reduce as WFT decreases. Additionally, the research identifies specific WFT thresholds correlating with maximum flowability and a 5% bleeding rate. These thresholds mark the critical point at which WFT ceases to influence flowability and delineate the maximum WFT that satisfies the bleeding rate requirements, respectively. These insights are important for optimizing the design of CLSM with PCE in terms of flowability and bleeding rate.

期刊论文 2024-10-11 DOI: 10.1016/j.conbuildmat.2024.138145 ISSN: 0950-0618

Construction spoil (CS), a prevalent type of construction and demolition waste, is characterized by high production volumes and substantial stockpiles. It contaminates water, soil, and air, and it can also trigger natural disasters such as landslides and debris flows. With the advent of alkali activation technology, utilizing CS as a precursor for alkali-activated materials (AAMs) or supplementary cementitious materials (SCMs) presents a novel approach for managing this waste. Currently, the low reactivity of CS remains a significant constraint to its high-value-added resource utilization in the field of construction materials. Researchers have attempted various methods to enhance its reactivity, including grinding, calcination, and the addition of fluxing agents. However, there is no consensus on the optimal calcination temperature and alkali concentration, which significantly limits the large-scale application of CS. This study investigates the effects of the calcination temperature and alkali concentration on the mechanical properties of CS-cement mortar specimens and the ion dissolution performance of CS in alkali solutions. Mortar strength tests and ICP ion dissolution tests are conducted to quantitatively assess the reactivity of CS. The results indicate that, compared to uncalcined CS, the ion dissolution performance of calcined CS is significantly enhanced. The dissolution amounts of active aluminum, silicon, and calcium are increased by up to 420.06%, 195.81%, and 256.00%, respectively. The optimal calcination temperature for CS is determined to be 750 degrees C, and the most suitable alkali concentration is found to be 6 M. Furthermore, since the Al O bond is weaker and more easily broken than the Si O bond, the dissolution amount and release rate of active aluminum components in calcined CS are substantially higher than those of active silicon components. This finding indicates significant limitations in using CS solely as a precursor, emphasizing that an adequate supply of silicon and calcium sources is essential when preparing CS-dominated AAMs.

期刊论文 2024-09-01 DOI: 10.3390/buildings14092954
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