The massive accumulation of waste PET plastic (WP) and coal gangue (CG) would induce a series of environmental problems such as causing soil and water pollution. For reducing the environmental pollution induced by these two wastes, this study attempts to utilize the combination of WP and CG into cement-based materials. Cement mortars incorporated with fine waste plastic (FWP) replacing part of sand and concrete blended with CG and coarse waste plastic (CWP) as part of coarse aggregate were prepared and their work-ability, mechanical strengths, dynamic elastic modulus (DEM), chloride ion permeability, hydration and microstructures were systematically investigated. In addition, metakaolin (MK) as a kind of active admixture was added into mortar or concrete and its effect of MK on the property of cement mortar or concrete was evaluated. The results show that the strengths of cement mortars containing various level of FWP decrease with increase of FWP and CG level. The mechanical strengths of concrete containing MK and 25-100 % CG and CWP are appropriate at different ages. Although the strengths of concrete blended with MK and wastes aggregate are lower than that of concrete without wastes, it is obviously higher than that of concrete only containing wastes but not MK. Its slump of fresh concrete significantly declines with CWP and CG contents growth. The coulomb electric flux and chloride migration coefficient of concrete at 28d generally increase with CG and CWP level, which indicates a declined tendency of resistance to chloride ion penetration. Its DEM for concrete measured with ultrasonic testing method slightly decrease with rise of CG and CWP content (25-100 %) and can give a basic prediction of strengths and chloride ion permeability. Hydration and microstructures tests including TG/DTA, MIP and SEM/EDS demonstrate that the pozzolanic reaction of MK can result in more gels generated and strengthen the ITZ between WP or CG and cement paste thus evidently improving its mechanical and durability of concrete when compared to the reference specimen without MK. Although the properties of concrete blended with CG and CWP as part of coarse aggregate are inferior to pure natural gravel contained concrete, its strengths and resistance to chloride ion permeability can achieve requirements of engineering structures.
The accumulation and discharge amount of coal gangue are substantial, occupying significant land resources over time. Utilizing coal gangue as subgrade filler can generate notable economic and social benefits. Coal gangue coarse-grained soil (CGSF) was used to conduct a series of large-scale vibration compaction tests and large-scale triaxial tests. The results indicate that the maximum dry density of CGSF initially increases and then decreases with the increase in fractal dimension. The stress-strain curves of the samples exhibit a distinct nonlinear growth pattern. Analysis of the compaction effect suggests that the compaction degree of CGSF should not be lower than 93%. As the confining pressure increases, the extent of failure strength improvement due to increased compaction decreases. Additionally, the failure strength of samples initially increases and then decreases with the increase in coarse particle content. A modified quadratic polynomial fractal model gradation equation was proposed to describe the gradation of samples after particle breakage. Based on this, a new quantitative index for particle breakage was established. Analysis of particle breakage in samples revealed that higher confining pressure and greater coarse particle content lead to increased particle breakage. The breakage exhibited a significant size effect, and the impact of particle gradation on sample breakage was greater than that of confining pressure. The stress-strain relationship of CGSF was analyzed by using a logarithmic constitutive model, and the correlation between model parameters and the newly derived particle breakage index was generated. A constitutive model incorporating particle breakage for CGSF was established, and its accuracy was validated.
This study utilizes polymers based on coal gangue and blast furnace slag to solidify engineering slurry with high silt content. Response surface methodology was employed to investigate the effects of polymer composition, alkali activator modulus, and coal gangue calcination temperature on the unconfined compressive strength of stabilized soil. Additionally, the study comprehensively characterized the thermal stability, pore structure, molecular bonds, mineral composition, and micro-morphology of the stabilized soils, and explored the mechanisms governing their strength development. The results demonstrate that the highest strength of stabilized soils is achieved with a slag to coal gangue ratio of 2.5:7.5, a water glass modulus of 1.2, and a coal gangue calcination temperature of 750 degrees C. Formation of calcium-aluminum-silicate-hydrate (C-A-S-H) and sodium-aluminum-silicate-hydrate (N-A-S-H) contributes significantly to the strength development. The presence of slag promotes early strength through C-A-S-H formation, while coal gangue facilitates N-A-S-H formation, supporting later-stage strength development by filling micropores. By applying alkali-activated calcined coal gangue-slag based cementitious materials to solidify engineering slurry, this research not only elucidates the mechanism of alkaliactivated calcined coal gangue-granulated blast furnace slag in slurry solidification but also promotes the utilization of industrial solid waste, providing new insights for environmental protection and resource recovery.
Considering the environmental protection and infrastructure needs for solid waste recycling and improvement of soil engineering properties, a fiber-gangue composite soil consolidation material is proposed to improve the mechanical properties of expansive soils and the workability to resist freeze-thaw (FT) cycling effects. The unconfined compressive strength (UCS) of the expansive soil was measured at varying FT cycles. Then, thermal-mechanical field simulation using Advanced Simulation for Engineering and Sciences (ABAQUS) numerical simulation software was conducted to analyze the stress-strain behavior of the model and compared with the UCS test results obtained during the laboratory test. After that, the microstructural characteristics of modified soil systems after FT cycles were carried out using scanning electron microscope (SEM) mapping to obtain the reinforcement mechanism. The investigation results indicate that the UCS of the modified expansive soil (MES) not only increased after experiencing 12 FT cycles, but also demonstrated a 20.1% reduction in UCS inhibition by the improver compared to plain-expansive soil (PES). Therefore the addition of fiber-coal gangue composite effectively amends the effect of FT cycles on the UCS of expansive soil. UCS test results suggest that a reasonable 9 mm long 0.3% fiber and 20% coal gangue ratio of the composite modifier is advantageous to the soil's mechanical properties. ABAQUS numerical simulations results the UCS strength of the specimens deteriorates gradually with the increase in the number of FT cycles, which is in agreement with the laboratory measured values. From the SEM observation, the PES samples were loose and the pores increased, while the coal gangue and the fibers of the incorporated expansive soil particles formed links between them, the structure was tight, the pores and cracks were reduced, and the compactness was improved.
The technology of loess solidification plays a crucial role in addressing issues such as soil erosion, with the key material in this process being the loess stabilizer. To tackle the high energy consumption problem associated with traditional loess stabilizers primarily composed of Portland cement, this study employed a more ecological sustainable alternative by incorporating solid waste coal gangue and magnesium oxysulfate (MOS) cement as a binding agent for consolidating loess. The alterations in bulk density, porosity, mineral structure, and microstructure of the consolidated soil with different MOS content were systematically investigated and validated. The pore size of MOS-solidified loess decreased significantly to a range of 0.04-3.60 mu m compared to 0.80-3.88 mu m for pure loess. Scanning electron microscope (SEM), energy dispersive spectrometer (EDS) and thermogravimetric (TG/DTG) analysis revealed that the addition of MOS binder generated hydrated magnesium silicate (M-SH), Mg(OH)2, and a small amount of 5Mg(OH)2 & sdot;MgSO4 & sdot;7H2O phase which filled the gaps between soil particles and bonded them together effectively. When the proportion of MOS binder added reached 11 %, the compressive strength of stabilized loess after curing for 28 days increased up to 9.4 MPa. After immersion in water for 24 h, the strength only decreased by 5.3%, with a softening coefficient of 94.7%. The test results consistently indicate that the enhancement in mechanical properties can be attributed to the binding effect facilitated by MOS. The ecological composite binder based on coal gangue and MOS demonstrates great potential in the field of soil stabilization.
In this study, carbide slag (CS) and coal gangue (CG) powder were utilized to enhance the properties of the subgrade soil. CS-CG stabilized soil underwent lab experiments to assess its mechanical properties and durability. Tests included unconfined compressive strength (UCS), compressive resilient modulus (CRM), and California bearing ratio (CBR) at stabilizer dosages of 5 %, 10 %, and 15 %. Additional tests, such as dry-wet cycling, salt solution immersion, permeability, leaching, thermogravimetric analysis (TGA), X-ray diffraction (XRD), scanning electron microscope (SEM) and mercury intrusion porosimetry (MIP), were conducted specifically for the 10 % dosage. The mechanical properties and durability were comprehensively analyzed, with a microscopic investigation into pore size. Furthermore, the soil-water characteristic curve (SWCC) of CS-CG stabilized soil is derived through MIP, providing insights into its impact on the material's strength. Results showcased favorable bearing capacity and durability of CS-CG stabilized soil. The optimal mixing dosage is 10%, with the best ratio being CS: CG= 70: 30. After 6 dry-wet cycles, UCS loss rate was 18.6%, comparable to 4% Portland cement (PC) stabilized soil. Dry-wet cycle characteristics surpassed PC and Lime stabilized soils. Immersion in a 5 % NaCl solution for 30 days yielded a UCS of 3.8 MPa at 28-day age, while exposure to 5 % Na2SO4 solution led to an 11.6 % strength decrease compared to NaCl. Permeability coefficient indicated low permeability akin to PC and Lime stabilized soils. Heavy metal content met standards, with minimal increase during cycles. Hydration products mainly comprised C-S-H gel, Ca(OH)2 crystals, and carbonate modification. Analysis suggested capillary and transition pores predominantly, with minimal macropores presence. Dry-wet cycles induced a marginal increase in pore size, with negligible overall impact. SWCC predicted water content (theta s) ranged from 30 % to 32 %, with a slight increase in matrix suction during dry-wet cycles. CS-CG stabilized soil shows favorable mechanical properties, durability, and environmental sustainability, indicating its potential as a substitute for traditional cement and lime treatments in subgrade soil reinforcement.
Constructing infrastructure on soft soils demands the implementation of ground improvement. This study proposed an eco-friendly method of stabilizing marine soil using a calcium carbide residue (CCR)-activated coal gangue (CG) geopolymer derived from industrial waste. Laboratory experiments were conducted to investigate the mechanical properties, durability performance, and stabilization mechanisms of stabilized marine soils under multiple wetting-dry cycles. The results highlighted the effectiveness of CG-CCR geopolymer by a content of 15% to achieve satisfactory strength gain over the engineering requirements. However, the largest decrease in strength (71.89%) was observed when the initial water content was beyond 1.5 times the liquid limit (LL). The optimum solution was proposed to have a geopolymer content of 15% or an initial water content of 1.25 & sdot;LL to exhibit the highest resistance to strength decay after 12 cycles. Compared with water intrusion, mass loss had a more significant effect on soil strength deterioration. The formation of noncrystalline or amorphous-phase reaction products effectively filled intergranular pores and reduced the void space between soil particles, improving the mechanical properties. The CG-CCR geopolymer was demonstrated to offer a promising solution for soil improvement in geotechnical engineering and waste reduction in industry as a soil stabilizer.
Traffic cyclic loading is the key factor that leads to the deterioration of the long-term service behavior of subgrade. A series of cyclic triaxial tests was carried out by the large-scale dynamic and static triaxial apparatus (LSDSTA) to study the dynamic behaviors of coal gangue subgrade filler (CGSF) under multi-step cyclic loading using the morphological characteristics of hysteretic curves (MCHC). MCHC was quantitatively characterized by four parameters, i.e., the unclosed degree (epsilon phl ), inclination of long axis degree (k hl ), area (S hl ) and fullness degree (alpha hl ). With the increase of dynamic strain, epsilon phl increases exponentially. k hl of the coal gangue sample first decreases and then shows an increasing trend with the increasing dynamic strain. The values of S hl are close to each other, and the energy dissipation in the sample is small. However, with the increase of dynamic strain, the specimen failure degree is increased, S hl increases exponentially, and the damping ratio increases. With the increase of dynamic strain, alpha hl increases approximately linearly. Confining pressure has a certain effect on the four parameters. There parameters can be recommended and used for quantitative analysis the dynamic behaviors of subgrade filler under traffic cyclic loading.
This paper investigated the improvement behaviors on dispersivity, water stability and mechanical properties of dispersive soil by calcined coal gangue (CCG) at 700 degrees C, and analyzed the modification mechanism. Dispersive soil specimens with different content of CCG (varying from 1 % to 10 %) were prepared and cured for 0-28 days. The dispersivity of the soil was determined by three different dispersivity determination tests. The tensile strength and compressive strength of the dispersive soil were determined by mechanical property tests. SEM, EDS, TG and XRD analytical methods were employed to reveal microstructure and mineral changes during modification. The results of the study show that the admixture of CCG and the prolongation of curing time contributed favorably to suppressing the dispersivity of the soil and enhancing the water stability, the compressive strength and tensile strength of the dispersive soil. With the increasing of CCG content and the prolongation of curing time, the dispersive soil gradually transforms into non-dispersive soil. Microstructural and mineral analysis indicate that CCG has pozzolanic activity, and the production of pozzolanic reaction products significantly increase the friction and cohesion among soil particles. The results show that the utilization of CCG as an admixture to improve the dispersive soil not only solves the disposal problem of waste gangue, but also optimizes the undesirable characteristics of the dispersive soil. And the modification effect of CCG on dispersive soil in practical engineering is confirmed by validation test.
Gasification slag (GS) is rich in SiO2, Al2O3, and Fe2O3, and has excellent particle size gradation, which has the potential to be employed as an aggregate in the field of controlled low-strength material (CLSM). Nevertheless, the large-scale application of GS as the fine aggregate for the preparation of CLSM has been scarcely investigated. In the present work, the applicability of replacing part of coal gangue (CG) with gasification coarse slag (GCS) as fine aggregate for the preparation of CLSM was investigated. The results revealed that using GCS as a fine aggregate improved the flowability of CLSM, and increasing the GCS content from 0 to 50 wt% improved the flowability from 250.0 to 280.0 mm. The 28-day compressive strength of all CLSM conformed to the requirements of ACI Committee 229. Compared to the Blank group, the 7- and 28-day compressive strength of the CLSM increased by 23.07% and 26.80%, respectively, at a GCS content of 50 wt%. The increase in compressive strength was mainly due to the pore-filling and hydration-promoting effect of the GCS, which made the structure denser. The dense structure reduced the expansion rate, absorption, and porosity rate of CLSM and increased the wet density. The optimal process parameter was the addition of 10 wt% of GCS. The results of heavy metal ion leaching showed that the optimal sample GS10 leached all heavy metal ions in much less than the limit values of GB 8978-1996 and GB 5085.3-2007. The results will provide new ideas and technical approaches for the large-scale application of GCS as the fine aggregate in CLSM.