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To address the low utilization rate of construction waste soil and the environmental impact of traditional cement solidification, this study investigates the effect of desulfurized gypsum and silica fume in synergy with cement for construction waste soil. The effects of solidifying material dosage, liquid-to-solid ratio, and mixing ratio on mechanical properties were analyzed. Optimal performance was achieved with the dosage of solidifying material was 20%, the liquid-to-solid ratio was 0.2, and the mixing ratio of desulfurized gypsum, silica fume, and cement was 2:1:1, meeting the requirements of the technical specification for application of road solidified soil (T/CECS 737-2020). This formulation is referred to as FS-C type solidified soil. A self-fabricated carbonation device was employed to assess carbonation methods, time, and curing age on the mechanical properties of solidified soil. Carbonation for 6 h post-molding significantly enhanced strength, while carbonation in a loose state led to strength reduction. SEM analysis revealed a denser microstructure in carbonated samples due to calcium carbonate and silica gel formation. Compared to traditional cement solidification, FS-C type solidified soil reduces cement consumption by 15%, decreases CO2 emissions by 299.25 g/m(3), and sequesters 85 g/m(3) of CO2. These findings highlight the potential of FS-C type solidified soil as an environmentally friendly alternative for construction applications.

期刊论文 2025-06-01 DOI: 10.1007/s10706-025-03172-5 ISSN: 0960-3182

Oxalate esters and isosorbide serve as intriguing polymer building blocks, as they can be sourced from renewable resources, such as CO2 and glucose, and the resulting polyesters offer outstanding material properties. However, the low reactivity of the secondary hydroxyl groups makes it difficult to generate high-molecular-weight polymers from isosorbide. Combining diaryl oxalates with isosorbide appears to be a promising approach to produce high-molecular-weight isosorbide-based polyoxalates (PISOX). This strategy seems to be scalable, has a short polymerization time (<5 h), and uniquely, there is no need for a catalyst. PISOX demonstrates outstanding thermal, mechanical, and barrier properties; its barrier to oxygen is 35 times better than PLA, it possesses mechanical properties comparable to high-performance thermoplastics, and the glass transition temperature of 167 degrees C can be modified by comonomer incorporation. What makes this high-performance material truly exceptional is that it decomposes into CO2 and biomass in just a few months in soil under home-composting conditions and it hydrolyzes without enzymes present in less than a year in 20 degrees C water. This unique combination of properties has the potential to be utilized in a range of applications, such as biomedical uses, water-resistant coatings, compostable plastic bags for gardening and agriculture, and packaging plastics with diminished environmental impact.

期刊论文 2024-06-18 DOI: 10.1021/acssuschemeng.4c02266 ISSN: 2168-0485
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