Plastic packaging has increased concerns about human health and the ecosystem due to non-biodegradability. Several biopolymers, such as cellulose, starch, and proteins, are being explored, and cellulosic residue from agricultural biomass is suitable to overcome this predicament. Herein, cellulosic residue fibers (ACR) extracted from alfalfa were used to prepare biodegradable films by solubilizing them in ZnCl2 solution and crosslinking the chains with calcium ions (Ca2+) and sorbitol. Box Behnken Design optimized the ACR, CaCl2, and sorbitol amounts against the responses of water vapor permeability (WVP), tensile strength (TS), and elongation at break (EB). The optimized film combination was found to be 0.5 g ACR, 461.3 mM CaCl2, and 1.05% sorbitol, making a 12 x 12 cm2 film, with a TS of 16.9 +/- 0.4 MPa, EB of 10.1 +/- 0.3%, and WVP of 0.47 +/- 0.11 x 10- 10 g.m- 1.s- 1. Pa- 1. It was translucent, blocked UVB light, followed Peleg's water absorption kinetics, displayed anti-oxidant activity, and biodegraded within 35 days at 24 % soil moisture. The ACR film extends the shelf life of strawberries by two more days compared to polystyrene film. The outcome offers a novel path to utilize and conserve natural resources and mitigate plastic perils, promoting a circular bioeconomy and sustainability and a win-win situation between the environment and farmers.

This paper aims to solve the problem of erosion sediment that negatively affects the quality of fallowed soil through the development of a new type of agricultural machinery. The transported erosion sediment will be quantified locally to evaluate the danger of these negative effects on the fallowed soil and on the functionality of the grass cover. Subsequently, a new type of machinery will be proposed for the remediation of eroded sediment and conservation of the fallowed soil. In various fallow research areas with different management methods (such as biobelts, grassed valleys, and grassed waterways), agricultural land affected by eroded sediment was examined, and appropriate machinery was designed to rehabilitate the stands after erosion events. By identifying the physical and mechanical properties of the soil, as well as the eroded and deposited sediment/colluvium, the shape, material, attachment method, and assembly of the working tool for the relevant mobile energy device were designed. The developed tool, based on a plow-carry system using a tractor, features flexible tools that separate the eroded sediment from the fallow land surface, transfer it over a short distance, and accumulate it in a designated area to facilitate subsequent removal with minimal damage to the herbaceous vegetation. The calculated erosion event was 196.9 m3 (179.0 m3 ha-1), corresponding to 295 tons (268.5 t ha-1) deposited from the area of 90 ha. Afterward, the proposed machinery was evaluated for the cost of the removal of the eroded sediment. Based on experience from the field, we calculated that 174 m3 per engine hour results in EUR 0.22 m-3. From the performed experiment, it is evident that the proposed machinery offers a suitable solution for eroded sediment removal locally, which prevents further erosion and subsequent sediment deposition in water bodies where the costs for sediment removal are higher. Moreover, we have proven the potential negative impact of invasive plant species because their seeds were stored in the sediment. Finally, it is credible to state that the proposed agricultural machinery offers an effective solution for the eroded sediment relocation, which subsequently can be used for other purposes and monetized. This results in an increase in the profitability of the erosion sediment removal process, which is already in place at the source before further transportation to aquatic systems where the costs for removal are significantly higher.

Substituting alternative materials and energy sources with forest biomass can cause significant environmental consequences, such as alteration in the released emissions which can be described by displacement factors (DFs). Until now, DFs of wood-based materials have included greenhouse gas (GHG) emissions and have been associated with lower fossil and process-based emissions than non-wood counterparts. In addition to GHGs, aerosols released in combustion processes, for example, alter radiative forcing in the atmosphere and consequently have an influence on climate. In this study, the objective was to quantify the changes in the most important aerosol emission components for cases when wood-based materials and energy were used to replace the production of high-density polyethylene (HDPE) plastic, common fossil-based construction materials (concrete, steel and brick), non-wood textile materials and energy produced by fossil fuels and peat. For this reason, we expanded the DF calculations to include aerosol emissions of total suspended particles (TSP), respirable particulate matter (PM10), fine particles (PM2.5), black carbon (BC), nitrogen oxides (NOx), sulphur dioxide (SO2) and non-methane volatile organic compounds (NMVOCs) based on the embodied energies of materials and energy sources. The DFs for cardboard implied a decrease in BC, SO2 and NMVOC emissions but an increase in the other emission components. DFs for sawn wood mainly indicated higher emissions of both particles and gaseous emissions compared to non-wood counterparts. DFs for wood-based textiles demonstrated increased particle emissions and reduced gaseous emissions. DFs for energy biomass mainly implied an increase in emissions, especially if biomass was combusted in small-scale appliances. Our main conclusion highlights the critical need to thoroughly assess how using forest biomass affects aerosol emissions. This improved understanding of the aerosol emissions of the forestry sector is crucial for a comprehensive evaluation of the climate and health implications associated with forest biomass use.

Post-harvest loss of fruits and vegetables, and health risks and environmental impact of current plastic packaging warrant new biodegradable packaging. To this end, cellulosic residue from agricultural processing byproducts is suitable due to its renewability and sustainability. Herein, soyhulls cellulosic residue was extracted, solubilized in ZnCl2 2 solution, and crosslinked with calcium ions and glycerol to prepare biodegradable films. The film combination was optimized using Box Behnken Design and film properties were characterized. The optimized film is translucent and exhibits tensile strength, elongation at break, water vapor permeability, hydrophobicity, and IC50 of 6.3 f 0.6 MPa, 30.2 f 0.9%, 0.9 f 0.3 x 10-10 gm-1 s- 1 Pa- 1 , 72.6 degrees, degrees , and 0.11 f 0.1 g/mL, respectively. The water absorption kinetics follow the Peleg model and biodegrade within 25 days at 24% soil moisture. The film extends the shelf life of raspberries by 6 more days compared to polystyrene film. Overall, the value-added soyhull cellulosic films are advantageous in minimizing post-harvest loss and plastic-related issues, emphasizing the principles of the circular bioeconomy.

Globally, approximately 2.12 billion tons of waste are annually disposed of, with laboratories significantly contributing across diverse waste streams. Effective waste management strategies are crucial to mitigate environmental impact and promote sustainability within scientific communities. This study addresses the challenges by introducing a novel method that transforms laboratory media waste into a valuable biopolymer named Agastic. The process involves repurposing agar extracted from bulk laboratory waste, blending it with bio-based plasticizers to produce Agastic sheets exhibiting mechanical properties comparable to traditional bioplastics. Using response surface methodology (RSM) and central composite design (CCD), optimal concentrations of agar (1.5-2.5% w/v), glycerol (0.25-1% v/v), and ethanolamine (0.5-1.5% v/v) were determined. Predictions from Design Expert software indicated impressive tensile strength up to 14.31 MPa for AGA-1 and elongation at break up to 52% for AGA-2. Fourier Transform Infrared Spectroscopy (FTIR) analysis confirmed agarose structural features in AGA-1 and AGA-2. Thermogravimetric analysis (TGA) showed polysaccharide-related breakdown between 38 degrees C and 280 degrees C in AGA-1, peaking at 299.36 degrees C; AGA-2 exhibited diverse thermal decomposition up to 765 degrees C, suggesting their biodegradable potential in packaging applications. Scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS) analysis confirmed nontoxic nature of Agastic and preserved morphological integrity in both samples. Soil degradation studies revealed AGA-1 and AGA-2 losing 71.31% and 70.88% of weight, respectively, over 15 days. This innovation provides a sustainable pathway to repurpose laboratory waste into eco-friendly bioplastics, particularly suitable for moisture-sensitive packaging such as nursery applications. These findings underscore Agastic films' promise as environmentally friendly alternatives to traditional plastics, supporting circular bioeconomy principles and significantly reducing ecological impacts associated with plastic waste.

Plastics are the most popular choice for packaging materials due to their strength, flexibility, and affordability. Their non-biodegradability, however, is an environmental concern and a serious human health issue that necessitates the development of sustainable and biodegradable alternatives. Towards this end, lignocellulosic residue from biowaste stands out as a viable option due to its robust structure, biocompatibility, biodegradability, low density, and non-toxicity. Herein, the lignocellulosic fiber from banana peel was extracted by alkali and bleaching treatment, solubilized in 68% ZnCl2 solution, and crosslinked through a series of Ca2+ ion concentrations, and films prepared. Results suggest that increasing Ca2+ ions concentration significantly increases the film's tensile strength but decreases moisture content, transparency, moisture absorption, water solubility, water vapor permeability, and percentage elongation. Films have a half-life of 15.26-20.72 days and biodegrade more than 50% of their weight within 3 weeks at a soil moisture of 21%. Overall, banana peel fiber could aid in designing and developing biodegradable films and offer a sustainable solution to limit the detrimental effects of plastics.

Plastics thrown out as trash are an everlasting threat to our biosphere and ecosystem. A sustainable remedy within our reach is the use of agricultural biomass. Herein, the lignocellulosic residue of switchgrass biomass, extracted using alkaline and bleaching treatments and solubilized in ZnCl2 solution followed by crosslinking with calcium ions, is used to develop biodegradable films. The films have been characterized for color, transparency, thickness, moisture, water solubility, water absorption, water vapor permeability, tensile strength, elongation, and soil biodegradation. Mathematical modeling of the water absorption and biodegradation behavior have also been studied. The films are transparent, possess high tensile strength and low water vapor permeability, and biodegrade completely within 40 days at 30% soil moisture. The tensile strength and whiteness of films increase with CaCl2 concentration, but elongation, water absorption, water solubility, water vapor permeability, and biodegradation decrease. Overall, the strong and biodegradable switchgrass residue-based films open up a new window of opportunities to design and develop reusable, recyclable, and compostable films from underutilized, inexpensive, and abundant agricultural biomass contributing to the circular bioeconomy in a friendly and sus-tainable manner.