Vegetation barriers are an important environmental characteristic of spent fuel road transportation accidents. Spent fuel vessels may be affected by force majeure factors during transportation, which leads to damage to spent fuel assemblies and containers and can cause radionuclides to gradually release from assemblies to vessels to the external environment. In this work, considering the growth periods of coniferous vegetation barriers and vessel type, a radionuclide dispersion model based on computational fluid dynamics (CFD) was established by adding a decay term and a pressure loss term. The simulations showed that, first, compared to the small (Type-II) vessel, the effects of fluid flow around the large vessel (Type-I) have a more significant impact on radionuclide dispersion. The backflow around the Type-I vessel causes leaked radionuclides to disperse towards the vessel, and the larger the vessel is, the more significant the rise of the leaked radionuclide plume tail will be due to the increased negative pressure gradient area. Moreover, the area contaminated exceeding the maximum allowable concentration by radioactivity for the Type-I vessel is reduced gradually with the growth of coniferous vegetation barriers due to the weakening of the backflow effect by growing vegetation. Second, compared to vegetation barriers of 15 years and 23 years, the horizontal distance exceeding the maximum allowable concentration of the leaked I-131 dispersion from Type II vessels near vegetation barriers for 12 years is the longest. The older the vegetation barrier is, the shorter the horizontal dispersion range, and the shape of radionuclide dispersion gradually transforms from flat to semicircular with vegetation barrier growth, but this could cause a greater radioactive accumulation effect near the leakage point, and the maximum concentration of leaked I-131 reached 0.54 kBq center dot m(-3) for leaked radionuclides from the Type II vessel under vegetation barriers of 23 years. In addition, improvement suggestions based on the proposed method are presented, which will enable the Standards Institutes to apply the research methodologies described herein across various scenarios. Environmental Implication: Compared to nonradioative pollutants, radioactive pollutants are intercepted by vegetation barriers and then migrate to the soil through leaves, stems, and roots, which can contaminate the surrounding environment. Considering the effects of vessel type and coniferous vegetation growth, a radionuclide dispersion model based on CFD was established. Suggestions for decontaminating radioactive pollution areas have been proposed based on the simulation results of hypothetical scenarios. The scenario applicability improvements based on the proposed model could assist relevant Standards Institutes to making improving measures.

Microplastic particles (MPs) have been detected in a variety of environmental samples, including soil, water, food, and air. Cellular studies and animal exposures reported that exposure to MPs composed of different polymers might result in adverse effects at the portal of entry (local) or throughout the body (systemic). The most relevant routes of particle uptake into the body are oral and respiratory exposure. This review describes the various processes that may contribute to the adverse effects of MPs. Only MPs up to 5 mu m were found to cross epithelial barriers to a significant extent. However, MPs may also exert a detrimental impact on human health by acting at the epithelial barrier and within the lumen of the orogastrointestinal and respiratory tract. The potential for adverse effects on human health resulting from the leaching, sorption, and desorption of chemicals, as well as the impact of MPs on nutritional status and dysbiosis, are reviewed. In vitro models are suggested as a means of (1) assessing permeation, (2) determining adverse effects on cells of the epithelial barrier, (3) examining influence of digestive fluids on leaching, desorption, and particle properties, and (4) role of microbiota-epithelial cell interactions. The contribution of these mechanisms to human health depends upon exposure levels, which unfortunately have been estimated very differently.

Nanostructure design is presented as one of the economically viable technical alternatives for increasing the efficiency of agrochemical use (fertilizers and pesticides) by reducing runoff, increasing foliar uptake and bioavailability, and reducing environmental impact. Nanomaterials (NMs) possess unique properties due to their nanoscale dimensions, typically ranging from 1 to 100 nanometers. At low concentrations, NMs can promote plant growth and development, but at higher doses, they may become toxic, causing oxidative stress, membrane damage, and disrupting key physiological processes. This review aims to comprehensively explore how this toxicity is influenced by NMs properties like chemical composition, dosage, surface structure, and solubility. Gaps in knowledge regarding NMs transport across the root surface and within plants hinder the rational design of NMs for targeted applications. Therefore, this review delves into the physical criteria that affect NMs uptake, translocation, and absorption in plants, as well as the interaction of NMs with plant cells, soil, and their environmental impact. Existing literature on NMs deposited on roots and foliar uptake mechanisms (via stomata, cuticle, trichomes, and necrotic patches) are also examined. The review also discusses how NMs penetrate plant cell walls and utilize plasmodesmata (PD) for translocation between cells, shedding light on the mechanisms and factors influencing these processes. The current knowledge highlights the participation of the symplast, including the PD, in the movement of NMs within the plant. These findings enhance understanding of how plant structure and NM characteristics influence their transport and distribution, aiding the rational design of NMs for controlled uptake and safe application in plants.

Examples of upscaling phenomena with experimental techniques are presented and discussed within the framework of compacted soils for hydraulic and environmental earthworks and engineered barriers for the energy sector. A series of laboratory experiments at different scales are presented and interpreted to focus on the need for experimental upscaling in compacted soils since distinctive behavioural features can only be detected at specific length scales. Permeability results on fine-grained soils and artificially prepared sand/bentonite mixture at different scales will be discussed with microstructural tests regarding 'dry' or 'wet side' compaction, element and mock-up tests on compacted soils in the laboratory, and field tests on a compacted trial embankment and demonstration test to explore anisotropic and heterogeneous features. The presented examples will help to motivate new experimental research subjects and promote experimental protocols at different scales ranging from mm-scale (micro), cm-scale element tests, dm-scale mock-ups and m-scale (trial/demonstration tests) to help understand and approach some fundamental questions observed at the application scale of compacted soils.

In this study, the sustainability of the electrokinetic remediation soil flushing (EKSFs) process integrated without and with adsorption barriers (EKABs) have been evaluated for the treatment of four soils contaminated with Atrazine, Oxyfluorfen, Chlorosulfuron and 2,4-D. To this purpose, the environmental effects of both procedures (EKSFs and EKABs) have been determined through a life cycle assessment (LCA). SimaPro 9.3.0.3 was used as software tool and Ecoinvent 3.3 as data base to carry out the inventory of the equipment of each remediation setup based on experimental measurements. The environmental burden was quantified using the AWARE, USEtox, IPPC, and ReCiPe methods into 3 Endpoint impact categories (and damage to human health, ecosystem and resources) and 7 Midpoints impact categories (water footprint, global warming potential, ozone depletion, human toxicity (cancer and human non-cancer), freshwater ecotoxicity and terrestrial ecotoxicity). In general terms, the energy applied to treatment (using the Spanish energy mix) was the parameter with the greatest influence on the carbon footprint, ozone layer depletion and water footprint accounting for around 70 % of the overall impact contribution. On the other hand, from the point of view of human toxicity and freshwater ecotoxicity of soil treatments with 32 mg kg(-1) of the different pesticides, the EKSF treatment is recommended for soils with Chlorosulfuron. In this case, the carbon footprint and water footprint reached values around 0.36 kg of CO2 and 114 L of water per kg of dry soil, respectively. Finally, a sensitivity analysis was performed assuming different scenarios.

Engineered soil barriers have been proposed to prevent rainwater infiltration into the underlying soil, thus improving stability of sloping ground. The use of engineered barriers on flat ground as means of preventing flooding has also been explored. This paper aims to provide proof-of-concept as to the potential efficiency of engineered barriers in minimising soil shrinkage and swelling arising from seasonal variations of water content and pore water pressures within the ground due to its interaction with the atmosphere. A series of 2-dimensional, hydro-mechanically coupled finite element analyses were conducted to this effect. Emphasis was placed on accurately modelling the stiffness of the underlying soil, accounting for its small-strain behaviour, as well as the hydraulic behaviour of all the layers involved. The results confirm that it is possible to engineer barriers to minimise shrinkage/swelling in greenfield, as well as urban, conditions and highlight the influence of barrier geometry and configuration, so that recommendations for the design of such barriers can be made.

Trichloroethylene (TCE) with trace concentrations is often detected in soils and groundwater, posing potential damages to public health. The elimination of TCE can be achieved through reductive dechlorination using zero-valent iron (ZVI). However, ZVI usually suffers from the presence of passive iron (hydro)oxides layer and low electron transfer rate, thus leading to the unsatisfactory reactivity. Herein, we fabricated oxalated ZVI (Ox-ZVI(bm)) by mechanical ball-milling of micro-scale ZVI and H2C2O4 center dot 2H(2)O to modify the ZVI surface composition. To be specific, the modification of the iron oxide shell by oxalic acid facilitated the generation of unsaturated coordination Fe(II), enhancing TCE adsorption. Furthermore, the formed FeC2O4 on the iron oxide shell improved electron transfer efficiency, contributing to the enhanced TCE reductive dechlorination. Impressively, the rate of TCE degradation by Ox-ZVI(bm) was 10-fold higher than that of ZVI(bm) without oxalate modification. Moreover, Ox-ZVI(bm) samples were filled in a laboratory Permeable Reactive Barriers (PRB) column to treat actual underground wastewater containing TCE pollutants. The effluent concentration of TCE maintained steadily below 0.21 mg/L for over 10 days, complying with the National Groundwater Class IV standard (GBT 14848-2017). This marks a significant step toward practical groundwater treatment.

Underground train-induced vibrations can cause nearby residents discomfort, damage to buildings, and disturbance for equipment. One of the most effective ways to reduce vibrations is using wave barriers along the propagation path of the waves. Many parameters are involved in determining the efficiency of these barriers: the barrier's dimension, distance from the source of vibration, and material property, to name a few. Simultaneous study of these parameters is complex since numerical analysis of alternatives is time-consuming. Therefore, in this study, by coupling the three-dimensional finite element method and an optimization algorithm, an attempt is made to provide a comprehensive solution to find the optimal wave barriers for Tehran metro line 4 as a case study. The current study evaluates two strategies: using in-filled trenches and topology-optimized barriers. In the first strategy, results show that soft-material trenches with maximum depth close to the observation point have the best performance. Further investigations on jet grout trenches show better performance in stiffer soil and lower train speed. Using dual trenches improves performance only up to 2%, so it does not provide a suitable option. For various practical reasons, there may be no tendency to use soft-material trenches, which perform well in vibration reduction. Therefore, in the second strategy, the improvement of a hard trench (jet grout) performance by topology optimization is investigated. According to this study, topology optimization is an effective method for improving barrier performance.

Grouting is normally undertaken to reduce the permeability of rock or soil formations and this process is used extensively in the construction of hydraulic structures such as dams, tunnels and in a wide variety of special cases. Even though the application of the grouting technique to reduce the permeability of rock formations has been reported in literature, no serious attempts are reported about the effective use of this technique to reduce the permeability of soil formations. In this paper, an attempt has been made to study the effectiveness of grouting in reducing the permeability of the granular medium. Constant head permeability tests were carried out on the sand medium treated with different grouting materials such as cement, bentonite, lime, locally available clay and different combinations of the above materials. By grouting with different grout materials (e.g., in the case of cement - bentonite grout) the permeability of the medium sand got reduced from 10(-4) m/s to 10(-9) m/s. The present study undoubtedly proves the effectiveness of using grouting as an efficient technique in reducing the permeability of sandy soils.