Numerous missions to the Moon have identified and documented volatile deposits associated with permanently shadowed regions. A series of science goals for the Artemis Program is to explore these volatile deposits and return samples to Earth. Volatiles in these reservoirs may consist of a variety of species whose stable isotope characteristics could elucidate both their sources and the processes instrumental in their formation. For example, the delta D of potential contributors to the deposits can be used to identify a uniquely light solar wind component. Because of the exceptionally low temperatures of these volatile deposits, examining and interpreting their stable isotope systems to fulfill Artemis science goals through sampling, preserving, curating, and analyzing these samples are far more difficult than for other sample return missions. Collecting and preserving the samples at cryogenic temperatures dramatically increases science yield but is technologically demanding and poses increased risk during transport.

From the scientific perspective, Artemis lunar missions focus on the south circumpolar region (SCR) mainly to investigate the existence and abundance of volatiles and to explore and sample ancient lunar deposits. The volatile distribution is primarily related to the cold traps in permanently shadowed regions, while the availability of ancient material is due to the proximity to the early lunar -2300 km diameter South Pole-Aitken (SPA) impact basin. One of the critical factors for future missions will be determining the geological structure and provenance (sources) of material at each candidate landing site, which can be predicted utilizing three-dimensional stratigraphic reconstructions of geological map units and crater ejecta deposits. This type of reconstruction permits a better understanding of candidate material that can be collected and analyzed at each site, and a ranking of landing sites can be formulated on this basis. Here, we present reconstructed geological cross-sections at Artemis landing sites using our recent SCR geological map and numerical modelling of crater ejecta thicknesses and their sequence.