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The increasing production of waste glass fiber reinforced polymer (GFRP) is causing severe environmental pollution, highlighting the need for an effective treatment method. This study explores recycling waste GFRP powder to substitute ground granulated blast furnace slag (GGBS) in synthesizing geopolymers, aiming to rapidly stabilize clayey soil. The impact of GFRP powder replacement, alkali solution concentration, alkaline activator/precursor (A/P) ratio, and binder content on the geomechanical properties and permeability of stabilized soil was thoroughly examined. The findings revealed that replacing GFRP powder from 20 wt% to 40 wt% lowered the unconfined compressive strength (UCS). However, soil stabilized with 30 wt% GFRP powder displayed the highest shear strength. This indicates that the incorporation of an appropriate amount of GFRP powder elevates clay cohesion. Furthermore, an increase in GFRP powder replacement improved permeability coefficient in the early stages, with minimal impact observed after 28 days. Scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS) analysis revealed a microstructural evolution of the stabilized soil, transitioning from a porous to a denser, more homogeneous composition over the curing period, which can be attributed to the formation of cluster gels enveloping the soil particles. Life cycle assessment (LCA) analysis indicated that the GFRP powder/GGBS geopolymer presents an alternative option to traditional Ordinary Portland Cement (OPC) binder, featuring a global warming potential (GWP)/strength ratio reduction of 6 %-40 %. This research offers a practical solution for effectively utilizing GFRP waste in a sustainable manner, with minimal energy consumption and pollution, thereby contributing to the sustainable development of soil stabilization.

期刊论文 2025-07-01 DOI: 10.1016/j.cscm.2025.e04204 ISSN: 2214-5095

Self-consolidating earth concrete (SCEC) addresses the long construction process of conventional earthen constructions and their structural limitations, while further efforts are needed to enhance its sustainability. This study explores the development of a kaolinite-based self-consolidating earth paste (SCEP) due to their blended powder system, incorporating raw and treated (calcined and ground-calcined) kaolinite under various activation techniques, such as water hydration, sodium hexametaphosphate (NaHMP), and sodium hydroxide (NaOH) activation. The synergistic effect of calcination and mechanosynthesis on rheological, mechanical, structural, and microstructural properties of SCEP were investigated. Mechanically treated kaolinite increased yield stress, plastic viscosity, storage modulus evolution, and build-up index, while delayed the strength development compared to the calcined kaolinite samples. Among the investigated activators, NaOH resulted in more promising structural build-up, storage modulus, and compressive strength development. These findings were elaborated with X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), calorimetry, thermogravimetric analysis (TGA), and scanning electron microscopy (SEM).

期刊论文 2025-06-06 DOI: 10.1016/j.conbuildmat.2025.141380 ISSN: 0950-0618

Fusarium graminearum poses a major threat to barley production worldwide. While seed priming is a promising strategy to enhance plant defense, the use of unconventional priming agents remains underexplored. This study investigates the protective effects of pre-infection camel urine seed priming on barley seedlings challenged with Fusarium graminearum, focusing on growth, disease resistance, oxidative stress, and defense-related responses. Barley grains were primed with camel urine and grown in both Fusarium-infested and uninfested soils. Fusarium infection initially triggered a sharp increase in oxidative stress markers reflecting an early oxidative burst commonly associated with defense signaling. However, in hydro-primed seedlings, this response persisted, leading to sustained oxidative damage and growth suppression. In contrast, camel urine priming modulated the oxidative burst effectively, initially permitting H2O2 accumulation for defense activation, followed by a rapid decline, resulting in an 84.53 % reduction in disease severity and maintenance of seedling growth under infection. This was accompanied by enhanced antioxidant defenses, as indicated by significantly increased activities of antioxidant enzymes, and a 145 % increase in total antioxidant capacity compared to control. Camel urine priming also showed a reduction in shikimic acid levels under infection, suggesting increased metabolic flux toward the phenylpropanoid pathway. Thus, phenylalanine ammonia-lyase activity, phenolic compounds, and flavonoids were significantly elevated. Antifungal enzymes, beta-glucanase and chitinase, also remained high in camel urine-primed seedlings, in contrast to their sharp decline in hydro-primed controls. These findings highlight camel urine priming as a promising, sustainable approach for managing Fusarium in barley.

期刊论文 2025-06-01 DOI: 10.1016/j.bcab.2025.103606

Resourceful utilisation of tailings waste remains a hotspot in global research. While silica-aluminate-rich copper tailings can serve as raw materials for geopolymer preparation, their high Si/Al ratio significantly limits the geopolymerization degree. This study investigates the feasibility of developing copper tailings-based geopolymers for road base applications, using copper tailings as the primary raw material supplemented with 30 % soft soil, 15 % fly ash, and 5 % cement. The effect of NaOH content on the strength characteristics of copper tailings-based geopolymers was explored by the unconfined compressive strength test and triaxial test. The mineral composition and microstructure of copper tailings-based geopolymers specimens were characterised based on the microscopic technique. The results show that: (1) With the increase of NaOH content, the unconfined compressive strength of the copper tailings base polymer increases and then decreases, and reach the maximum value when the NaOH content is 1 %. Compared with the sample without NaOH, the addition of 1 % NaOH increased the unconfined compressive strength by 47 % at the early stage and 69 % at 28d curing age. (2) An optimal NaOH content significantly improves the shear performance of the copper tailings-based polymer, primarily by enhancing its cohesion. Triaxial test results demonstrate that 1 % NaOH addition increases cohesion by 73 % at 28d curing age. (3) The NaOH promotes the formation of geopolymer gel, refines the pore structure, and increases sample density, thereby enhancing strength. Overall, the research results can provide a reference for the application of copper tailings solid waste in roadbed materials.

期刊论文 2025-06-01 DOI: 10.1016/j.jece.2025.117112 ISSN: 2213-2929

Solid-fluidization transition-induced flow-like events pose significant threats to both ecological systems and human society. This geophysical phenomenon undergoes a continuous and catastrophic solid-fluidization-solid retransition, which often leads to severe disasters. A series of flume and rheological tests were conducted to explore the continuous solid-fluidization-solid retransition mechanism of sedimentary loess. The results showed that the flow distance after phase retransition increased by 39.5% compared with the first flowslip distance. With increasing rainfall intensity, the moisture content during phase transition tended to decrease while the time required for reactivation lengthened. Rheological analyses revealed that the reduction and recovery of storage modulus exhibited by thixotropy is a crucial mechanism in the phase retransition of soil, and they have significant time-concentration dependence. A higher soil water content leads to a longer structural recovery time and stronger thixotropy, which agrees well with the results of flume tests. Our experimental data NSav and NBag showed a positive power-law relationship and had similar fitting coefficients to the field case data, indicating that our experimental results have successfully captured the kinematic and rheological characteristics of real mudflow events. This study suggests that thixotropy can be used to interpret complex phase retransition processes in mudflow and can also help to explain the hypermobility and reactivation of many large geophysical processes, such as pyroclastic flows.

期刊论文 2025-05-01 DOI: 10.1029/2024JF008123 ISSN: 2169-9003

The use of ordinary Portland cement for the stabilisation of granular materials in road construction undermines the effort on sustainability made by using recycled aggregate in substitution of natural ones. This requires the use of low-impact binders so that the road construction industry complies with the prevailing environmental regulations. This study compares the mechanical and environmental properties of construction and demolition waste (CDW) aggregates stabilised with different binders: (i) a Portland-limestone cement as a reference, (ii) a pozzolanic cement, (iii) an experimental pozzolanic cement containing waste clay from the lightweight aggregate production, and (iv) a binder with alkali-activated CDW fines. In the laboratory experiments, both strength and resilient properties were considered, while the environmental impact was assessed in a cradle-to-gate scenario through a life cycle analysis (LCA). The stabilised mixture with pozzolanic cement achieved comparable strength and stiffness while exhibiting a lower environmental impact than the mixture containing Portland-limestone cement. The addition of waste clay to the pozzolanic cement significantly reduces its environmental impact albeit more binder is required to compensate for the lower mechanical properties. The alkaline activation of the fine particles in the CDW aggregate enabled the creation of a stabilised mixture with high strengths and resilient modulus. However, this alternative stabilisation technique requires further optimisation to mitigate the significant environmental impact. The engineering evaluations of the stabilised granular mixtures studied have considered both mechanical and environmental factors intending to contribute to the scientific debate on how to make roadworks sustainable and conserve natural resources.

期刊论文 2025-04-11 DOI: 10.1016/j.conbuildmat.2025.140705 ISSN: 0950-0618

This study investigates the mechanisms controlling multiphase landslide reactivation at red soil-sandstone interfaces in subtropical climates, focusing on the Eastern Pearl River Estuary. A significant landslide in September 2022, triggered by intense rainfall and human activities, was analyzed through field investigations, UAV photogrammetry, and geotechnical monitoring. Our results demonstrate that landslide evolution is governed by the interplay of geological, hydrological, and anthropogenic factors. Key findings reveal that landslide boundaries are constrained by fractures at the northern trailing edge and granite outcrops in the south, with deformation progressing from trailing to leading edges, indicative of a creep-traction failure mode. Although the landslide is stabilizing, ongoing deformations suggest disrupted stress equilibrium, emphasizing the risks of future reactivation. This work advances the understanding of progressive landslide dynamics at soil-rock interfaces and provides critical insights for risk mitigation in subtropical regions.

期刊论文 2025-04-10 DOI: 10.3390/w17081139

This study aims to understand the effect of injection rate on injection-induced fracture activation in granite. We performed water injection-induced slip tests on samples containing either a smooth or a rough fracture at four different injection rates under undrained conditions and monitored the acoustic emission (AE) signals during the tests. Experimental results reveal that the critical activation fluid pressure is related to the injection rate, pressure diffusion rate, stress state, and fracture roughness. For the smooth fracture, as the injection rate increases, the critical activation fluid pressure increases significantly, while the injection rate has little effect on the critical activation fluid pressure of the rough fracture. The quasi-static slip distance of fractures decreases as the injection rate increases, with rough fractures exhibiting a greater overall slip distance compared to smooth fractures. The number of AE events per unit sliding distance increases with the injection rate, while the global b value decreases. These results indicate that higher injection rates produce more large-magnitude AE events and more severe slip instability and asperity damage. We established a linkage between fluid injection volume, injection rate, and AE events using the seismogenic index (S). The smooth fracture exhibits a steadily increasing S with the elapse of injection time, and the rate of increase is higher at higher injection rates; while the rough fracture is featured by a fluctuating S, signifying the intermittent occurrence of largemagnitude AE events associated with the damage of larger fracture asperities. Our results highlight the importance of fracture surface heterogeneity on injection-induced fracture activation and slip. (c) 2025 Institute of Rock and Soil Mechanics, Chinese Academy of Sciences. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/ 4.0/).

期刊论文 2025-04-01 DOI: 10.1016/j.jrmge.2024.08.011 ISSN: 1674-7755

Ancient landslides with platform geomorphology occasionally reactivate, posing serious geohazards. On September 9, 2021, persistent heavy rainfall triggered the reactivation of the Dahekou ancient landslide within a gently sloping geomorph0logy at the core of Zhangjiantan syncline in China's western Qinling-Daba Mountains. This event caused one death, damaged 80 houses, and blocked the Yushui River. This study reconstructs the sliding process of the Dahekou landslide and deciphers the complex landslide initiation mechanisms through field surveys, unmanned aerial vehicle (UAV) imagery analysis, drilling, electrical resistivity tomography (ERT) and small baseline subset-interferometric synthetic aperture radar (SBAS-InSAR) monitoring. We divide the sliding process of the Dahekou landslide into three stages. Two new landslides (#1 and #2) occurred at 18:30 on September 9, 2021. Subsequently, the ancient landslide (#3) slid in the 230 degrees direction at approximately 20:30 on September 9, 2021, then changed the direction to 170 degrees-240 degrees at 22:30 on the same day, and moved in the direction of 300 degrees at 10:00 the next day. Finally, the reactivated ancient landslide (#3) formed two partially sliding masses, with volumes of approximately 158x10(4) m(3) and 160x10(4) m(3), along the directions of 170 degrees-240 degrees and 300 degrees, respectively, damaging 80 houses and blocking the Yushui River. Field surveys suggest that new landslides #1 and #2 are rock landslides and soil landslides, respectively, with volumes of approximately 230x10(4) m(3) and 7.49x10(4) m(3). Compared with the InSAR data, the new landslide #1 thrust the ancient landslide #3, with an uplift velocity rate of 22.68 mm/a at the rear edge, from September 2020-September 2021. An analysis of drill hole data reveals that the bedding in the landslide area has complex geological conditions, comprising mudstone prone to slipping with different degrees of weathering. Notably, the core of the Zhangjiatan syncline sits on the sliding bedding of the ancient landslide, contributing to a change in the sliding direction. This comprehensive study reveals that the landslide #1 loading and thrusting, the persistent and heavy rainfall, and the complex geological conditions influenced the reactivated ancient landslide. Considering the intricacies of landslide failure mechanisms, we advocate for giving more attention in the future to the zone of potentially slip-prone strata located at the edge of ancient landslides.

期刊论文 2025-04-01 DOI: 10.1007/s11629-024-9130-x ISSN: 1672-6316

Traditional disposal methods such as landfilling and land reclamation are insufficient to mitigate the environmental impact of construction spoil, making non-sintered blocks a promising approach for resource utilization. This study investigates the production and performance of steel slag soil blocks as an alternative to conventional cement-based materials for non-sintered blocks. The optimal manufacturing parameters were identified as a sodium silicate solution with 6% Na2O, 30% steel slag content, a liquid/solid ratio of 0.18, and a forming pressure of 10 MPa, achieving a peak compressive strength of 14.46 MPa. Further, the synergistic combination of alkali activation and carbonation enhanced compressive strength to 17.4 MPa, attributed to the development of a compact microstructure characterized by a honeycomb-like C-(A)-S-H gel and well-crystallized, triangular-shaped aragonite. However, durability tests under freeze-thaw and wet-dry cycles revealed that carbonation can detrimentally affect performance. The transformation of C-(A)-S-H gel into calcium carbonate, with relatively weaker cementitious properties, led to internal cracking and surface detachment. Micro-CT analysis confirmed ring-like patterns under freeze-thaw conditions and diagonal cracks during wet-dry cycling, whereas reference blocks incorporating 30% ordinary Portland cement maintained superior compactness with no cracks. These findings suggest that although the alkali activation and carbonation process enhances early strength, further optimization is necessary to improve long-term durability before broader application can be recommended.

期刊论文 2025-04-01 DOI: 10.3390/ma18071596
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