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The volumetric instability of expansive soils caused by moisture variations often leads to catastrophic consequences, including geohazards, structural damage, and high repair costs. The situation becomes more intricate when expansive soils are subjected to the chemical composition present in the fluid. This study investigates the chemical effects on the swelling and mechanical properties of expansive soil through comprehensive experiments. The results indicate that chemical effects inhibit swelling deformation and pressure, while saline solutions enhance effective stress and shear strength, evidenced by upward shifts in the strength envelope. Notably, the chemical influence on bentonite exhibits a threshold around 0.5 mol/L NaCl solution; below this threshold, soil properties change significantly with increasing solution concentration, whereas beyond it, the impact diminishes. Additionally, this study considers the effects of infiltration methods, initial moisture content, and shearing rate on shear strength. Different infiltration methods result in similar maximum volume variation and swelling pressure despite varied duration curves, with double infiltration reacting the fastest, top infiltration reacting slower, and bottom infiltration reacting the slowest. For soil samples with identical solutions, low initial moisture content causes notable strain softening and peak shear strength, while higher moisture reduces strain softening and peak strength. Under the same conditions, rapid shearing leads to higher shear strength.

来源平台：INTERNATIONAL JOURNAL OF GEOMECHANICS